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A Total Scattering Study of Local Structure in BIMEVOXes
The BIMEVOXes are an important family of fast oxide ion conducting solids that exhibit very high conductivities at low and intermediate temperatures. A study of local ordering... -
Vacancy Distribution in Praseodymium Doped Ceria
Doped cerias are currently being used as oxide ion conducting electrolyte materials in solid oxide fuel cells (SOFCs). Depending on the nature and concentration of the dopant... -
Investigating variation of back stress in 316H during high temperature asymme...
Deformation in polycrystalline material is inhomogeneous. Our previous study using neutron diffraction has shown due to these inhomogeneities, during high temperature cyclic... -
Na-Dynamics in Solid Ionic Conductors: 11Al2O3-Na2O and Na2Ti3O7
We propose to measure the quasielastic neutron scattering (QENS) spectra to study the diffusion dynamics in beta- alumina (11Al2O3-Na2O) and Na2Ti3O7. The measurement of QENS... -
Correlating local structure with properties in piezoelectrics, and multiferro...
Discovery and development of advanced materials requires understanding and control of the relationship between composition, structure and function. Traditionally, design has... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride... -
Anomalous fast diffusion of Cu ions in superionic and liquid phases of CuI
CuI is well-known to exhibit the superionic behaviour in the high temperature solid state (α-phase), where the mobile Cu ions migrate among the interstices in the f.c.c.... -
Neutron scattering investigation of Lithium diffusion mechanism in the Li-ion...
The compound LixCoO2 has attracted lots of attention in the recent years because of its application as cathodes in Li-ion batteries. The diffusion pathway of Li- ions within a... -
Structure/Conductivity Relationship in Doped Bismuth Tantalate Solid Electrol...
A detailed study of the temperature and compositional variation of defect structure in doped bismuth tantalates is proposed. Tantalum doping into Bi2O3 can achieve d-phase... -
Towards intermediate temperature diffusion: oxygen dynamics in Ce(Nb,V)O4+d
CeNbO4+d (0 <= d <= 0.33) displays mixed ionic-electronic conductivity at ~800 °C, where it adopts the tetragonal scheelite structure. Prior research has shown that... -
The structure and thermoelastic properties of jadeite, NaAlSi2O6, above room ...
Jadeite, NaAlSi2O6, is a rare, but geologically important clinopyroxene. In the upper part of the transition zone between the upper and lower mantle most pyroxenes are... -
Superstructure in bismuth rich substituted bismuth oxides
A study of superlattice ordering in substituted bismuth oxides is proposed. Bismuth rich compositions at the 14:1 B:M (where M = W/La and Ta) ratio will be investigated. These... -
In-situ neutron diffraction studies on proton conducting oxides (CaxLa1-x) ~6...
Rare-earth tungstates have recently attracted significant attention due to its high-temperature proton or mixed proton-electron conductivity. The proton conductivity in La6WO12... -
Magnetic structure determinenation in the antiferroelectric - antiferromagnet...
This proposal seeks to explore a multiferroic material new to science, that of the antiferroelectric ¿ antiferromagnetic ceramic Bi0.8Nd0.2FeO3. This new class of material is of... -
Total Scattering Study of Hexagonal and Rhombohedral Bi2O3 Based Electrolytes
Bismuth oxide based electrolytes have been widely studied due to their high oxide ion conductivity. The d-phase of Bi2O3 shows the highest known oxide-ion conductivity of any... -
QENS studies of conductivity/hydride diffusion in barium hydride
BaH2 has application in hydrogen storage technologies. We propose to study BaH2 by Quasi-elastic neutron scattering. We will perform scans at different temperatures for up... -
Variable Temperature Study of Structural Transitions Occurring In Clusters of...
Catalysts lower energy costs of a wide range of important processes, from the production of oil and plastics to the preparation of drugs and paints, making these products... -
Programme Access Rosseinsky/Claridge
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QENS studies of hydride ion diffusion in alkaline earth hydrides
We propose to study hydride ion diffusion in AEH2 (AE = Ca and Ba) using the QENS technique. We have recently demonstrated that the charge carrier in these materials are hydride... -
The use of INS to characterise prototype methane reforming catalysts over a r...
Previous work by the experimental team has successfully examined methane reforming catalysts using CO2 as the oxidant. Unfortunately, the progression to using steam as the...