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Thermal expansion of hexa-halogenated benzenes: C6Cl6, C6Br6, C6I6.
The aim of the present proposal is to complete a systematic study on the effects of isotopic and chemical substitution on the thermal expansion and vibrational properties of... -
Structure and cation ordering in A2Sn3Q7-type phases (A=In, Cr; Q= S, Se)
We wish to exploit the contrast afforded by neutrons to study the ordering of In and Sn cations in indium tin chalcogenides. Cation ordering has been inferred from spectroscopic... -
Has residual solvent an impact on the dynamics of PMMA ultra thin films?
Polymeric films thinner than a 100 nm exhibits a variation of the glass transition temperature of a few tens of degrees and can brake up into discrete islands when heated near... -
The magnetic excitation spectrum in Fe1.07Te
We propose to investigate the high energy magnetic spectrum in Fe1.07Te. We have previously investigated the fluctuations in Fe1.14Te in the incommensurate phase and have found... -
Misfit and Misfit Release in Co-Co3(Al,W) Superalloys
The effect of alloying additions (Ni, Fe, Cr, Ta, Mo, V, Ti, Si) on the misfit of developmental Co-Al-W alloys will be examined using Polaris. The Co3(Al,W) precipitate phase... -
A high-temperature neutron powder determination of the phase transition and c...
Cu2ZnSnS4 (CZTS) is a solar cell material of great interest. However the material when fabricated, although of high symmetry, contains substantial defect concentration and a... -
INS STUDY OF BIOCHAR AS SOLID ACID CATALYSTS
Pyrolysis is considered as a sustainable way to generate energy from bio-oil, however, biochar – a solid residue by-product– is inevitably produced in the production line. We... -
Phase behaviour and dielectric phenomena in bismuth niobate energy storage ma...
Bismuth niobate (BiNbO4) is widely used in multilayer RF and microwave components such as capacitors and chip layer capacitors. This compound exhibits two main structural forms... -
Further investigation of the methanol to gasoline reaction over ZSM-5 using INS
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously... -
Analysing intermediates of a CO2 insertion reaction using simultaneous operan...
Atmospheric levels of CO2 are increasing at uncontrolled levels and as such methods of CO2 utilisation are being researched. A key reaction for this purpose is the coupling of... -
The chemisorption of hydrogen over a Raney cobalt catalyst: An INS investigation
Building on a successful programme investigating aspects of iron based Fischer-Tropsch synthesis (FTS) catalysts, it is opportune to extend that work to include Co FTS... -
Neutron Spin resonance in the Fe-based silicide superconductor LaFeSiH
The iron-based superconductors (Fe-SC) are one of the most active and challenging topics in condensed matter physics. Very recently some of us (F. Bernardini et al.) have... -
In-situ thermoelectric measurements of copper chalcogenides
Thermoelectric devices are capable of converting thermal energy directly into electrical energy. The efficiency of a device is related to the characteristics of the materials of... -
Correlation between structure and properties in Bi0.7La0.3FeO3
Bi0.7La0.3FeO3 has received extensive attention in the past years, since this compound exhibits simultaneously ferroelectricity and ferromagnetism at room temperature. Despite... -
Thermoelastic Properties of Thermoelectric PbSe I HRPD
We propose to study the effect of pressure and temperature on the crystal structure and the elastic properties of lead selenide, an important material for conversion of waste... -
Investigation of the nature of organic surface species formed on Au-based sup...
The objective of this proposal is to spectroscopically identify the nature of surface species formed during the addition of tert butyl hydroperoxide onto the surface of the... -
Studying the strength of acid sites in an industrial ZSM-5 catalyst: MAPS
As part of an on-going programme of work to better understand critical factors in the methanol-to-hydrocarbon process over ZSM-5 zeolite catalysts, it is becoming increasingly... -
MAPS Investigation of the decompositon of LiNH2BH3
Ammonia borane, NH3BH3, has been extensively studied as a potential hydrogen storage material because of its high hydrogen content (19.6wt%) and relatively low decomposition... -
High-energy spin excitations in antiferromagnetic metal of (Mn,Fe)3Si
Since magnetism in Fe-based superconductors (SCs) show many similarities to that in Cr, investigation of the overall spin dynamics of antiferromagnetic (AF) metal will give... -
Investigation of the impact of mechanical twinning on the thermal expansion b...
We request three days of beam-time on POLARIS to investigate the influence of thermally-induced twinning on the thermal expansion behaviour of polycrystalline calcite....
