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Kinetics of Hydrogen Abstraction in Alkanes by Mu Reactivity studied by RF Re...
Hydrogen abstraction reactions are key steps in free radical mechanisms that dominate the combustion and atmospheric chemistry of the alkane hydrocarbons and, as such, merit... -
Aggregation and miscibility of dimethylcarbonate in hydrocarbon fuel model
Green Lizard Technologies are undertaking performance trials with dimethylcarbonate as a blend component in diesel fuels to reduce carbon particulate emission. Here,... -
Mixed gas hydrates at high pressure
High pressure gas hydrates offer considerable potential for gas storage applications if methods can be devised to stablise them at lower pressures. This proposal is form... -
Denitrogenation of fuel oils using hydrated choline chloride:malic acid DES
Deep Eutectic Solvents (DES) are complexes of organic salts and neutral hydrogen bond donors. They are tuneable, low volatility liquids that are environmentally benign.... -
The Structure of Liquid DMAc (Disordered Materials Express)
We will use neutron diffraction with isotopic substitution to study Dimethylacetamide (DMAc) in the hope of establishing this amide solvent's structure. Dimethylacetamide is a... -
Investigating the mechanisms for the in situ growth of metal oxide nanopartic...
Composites materials that combine the flexibility and mechanical robustness offered by polymers with the functionality displayed by metal oxide nanoparticles offer new insight... -
Pressure-temperature phase diagram of of the Jahn-Teller transition in LaMnO3
The parent compound LaMnO3 of the hole-doped colossal magnetoresistance materials La1-xAxMnO3 (A = Ca, Sr, Ba etc.) has attracted much interest from condensed matter scientists.... -
Gas condensation and fluid behaviour in nanoporous ZIF-8 materials upon gate...
This proposal aims to study condensation transitions in nanoporous flexible materials by means of wide Q-range neutron diffraction. We plan to perform an in-situ gas... -
Proton Conducting Pathways in Metal-Organic Frameworks
Recently metal-organic frameworks (MOFs) have been developed with high intrinsic proton conductivity and with potential for use in low temperature fuel cells. Their... -
The structure of solvents around 2d graphene oxide nanoparticles
Graphene oxide (GO) is an important starting material for developing chemically modified graphene for use in a variety of important technical applications that include... -
Understanding the structure of sodium laureth sulfate and NaCl mixtures in water
The objective of this research is to understand the detailed structure of water-surfactant solutions as a function of concentration of salt. This is important as these materials... -
The hydration and ordering of lamellar block copolymer films prior to the for...
For polymer vesicles to act as effective molecular delivery systems we must efficiently encapsulate a molecular payload within the vesicle. We would like to use neutron... -
Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
Exploration of the pressure-induced amorphization and glassy states of THF-cl...
Clathrate hydrates (CHs) are ice structures in which water molecules (host) form cages through hydrogen bonds. The cages can accommodate various types of molecules (guests),... -
Monitoring the formation of surface-enriched PbI2 in atmospherically treated ...
Metal halide perovskites have enabled remarkable advancements in low-cost, high-performance optoelectronics, however their performance potential is restricted by an incomplete... -
Solvation structures of cyclic compounds: the crown ethers
Crown ethers are cyclic molecules formed by joining ether groups into a ring. These compounds have many interesting solution properties, including their ability to bind strongly... -
Study of gas absorption in MCM41.
We have studied the absorption of nitrogen gas in MCM41 on NIMROD at a pressure of 1 bar and at temperatures to 87K (A K Soper and D T Bowron, Chem. Phys. Lett., DOI:... -
Developing QLCR spectroscopy as a muSR tool
Quadrupolar level crossing resonance (QLCR) in muSR of solid state systems with diamagnetic muon states in proximity to quadrupolar nuclei was discovered many years ago, however... -
Copy of: Division of the supercritical fluid state into liquid- and gas-like ...
In recent years, the long-standing belief that beyond the critical point, matter exhibits no clear transition between liquid-like and gas-like states has been questioned. A line... -
Diffusion Kinetics in Multilayer Organic Films for OLEDs
Conjugated organic semiconductors form an exciting class of materials that can be used in a variety of cutting edge technologies including organic light-emitting diodes (OLED),...
