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Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
Gold, in its nano-scale, has been found to be very effective catalyst for oxidation reactions. More recently, it was shown that supported Au-Pd catalysts can be used for... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
Improper ferroelectricity in hexagonal tungsten bronzes
We address the detailed atomistic mechanism of ferroelectricity in a new family of oxides typified by the composition CsNbW2O9. Contrary to the mechanism in most ferroelectrics,... -
Analysing intermediates of a CO2 insertion reaction using simultaneous operan...
Atmospheric levels of CO2 are increasing at uncontrolled levels and as such methods of CO2 utilisation are being researched. A key reaction for this purpose is the coupling of... -
Proton dynamics of supported palladium/gold entities in technical catalysts f...
Vinyl acetate is used on the million tonnes per year scale for the production of various grades of polyvinyl acetate, a component in paper, adhesive and textile applications.... -
The role of Disorder in Phase Transitions in some manganese Perovskites
The aim of this work is to understand the origin of the difference in the behaviour between the two doped manganites Sr0.65Pr0.35MnO3 and Sr0.70Ce0.30MnO3. The hypothesis we... -
The ferroelectric phase transition in Dion-Jacobson layered perovskites - con...
Ferroelectricity in the Dion-Jacobson (DJ) family of layered perovskites arises from a 'trilinear coupling', whereby two non-polar lattice modes interact in such a way to... -
YMnO3-x : Mn(I) in a mixed metal oxide ?
Topotactic reduction of YMnO3 with CaH2 yields three new reduced phases. Two of these phases appear to have compositions close to YMnO2.5 but with very different anion vacancy... -
Understanding the "post-perovskite" structure (I): the Behaviour of CaPtO3 at...
Recently, our view of the Earth¿s lower mantle changed dramatically. It had been thought that two major phases were present throughout all of the lower mantle:... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Magnetic excitations in the S=1/2 ferromagnetic semiconductor Lu2V2O7
Lu2V2O7 is a rare example of an S=1/2 pyrochlore. The fact that it is a ferromagnet with Tc=70 K belies the fact that it has some truly remarkable properties. These include the... -
Structural Aspects and Magnetic Order in Fe based perovskite oxide fluorides ...
In this work, we will investigate the structures (crystallographic and magnetic) of Mn5VO8 and a range of Fe containing perovskite oxide fluorides. In terms of the former, this... -
Mechanism of hydride-ion mobility in a novel oxide-hydride
This proposal requests 7 days of beamtime on the quasielastic neutron scattering spectrometer OSIRIS to investigate the mechanism of hydride ion mobility in the recently... -
Resolving manifold setting dynamics in protiated and D2O based portland cement.
Previous NCS measurement on glass biocements revealed that setting is non-monotonic. Recent determinations using VESUVIO (2016-Apr) for Portland cements showed similar... -
Can INS measurements access hydrocarbonaceous overlayers on heterogeneous hyd...
This application seeks to discover whether the catalyst handling protocols refined for INS measurements of a variety of heterogeneous catalytic systems can be further exploited... -
Compressible Liquids
Liquids are commonly known to be incompressible. However, a recently invented class of materials called Porous Liquids, which exhibit permanent porosity in the liquid phase, may... -
Understanding Chemical Expansion in Perovskite Oxides: Impact of Long-Range D...
"Chemical expansion" occurs when some ceramics expand upon releasing oxygen. Their ability to effectively "breathe" oxygen makes them of use in sustainable energy... -
Possible high-temperature polar phases in the [110] layered perovskites NdBaI...
Geometric ferroelectrics are an unusual and rare class of materials which exhibit spontaneous electrical polarisation due purely to 'geometric' effects, i.e. caused by atomic... -
Microstructural orientation mapping with a neutron beam
We propose to develop the means to measure the orientations, phases and strains of individual crystal grains within a polycrystal using neutrons. Such measurements have... -
MAPS commissioning
This dataset has no description
