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In-situ diffraction and TGA of the hydration reaction of proton conducting pe...
Here the use of the IGAN system for in-situ TGA and neutron diffraction is proposed in order to study the de-hydration of four proton conducting materials. The selected... -
Reflectometry studies of the mechanism of formation of mesoporous silicate fi...
Surfactant-silica self-assembly processes have been extensively studied since the discovery of M41S mesoporous materials in 1992. Mesoporous silicate films can be grown from... -
Structural studies of thermochemical and phase-change naterials for heat storage
This proposal seeks to study three systems associated with heat-storage applications using in situ neutron powder diffraction. The first experiment will focus on a sample of... -
Investigation of the excitation spectrum in the 1D distorted diamond chain Az...
We propose to investigate the excitation spectrum of azurite in both zero field and applied fields up to 7T. Using inelastic neutrons on OSIRIS we hope to clearly resolve the... -
Hydrogen from ammonia using lithium imide metal nitride composites
Light metal amides and imides are a new class of highly active ammonia decomposition catalysts. Indeed, composites of lithium imide and transition metal nitrides are likely to... -
Building a comprehensive understanding of cation ordering in the commercial c...
The objective of the proposed experiment is to develop an understanding of the Li/Ni/Mn ordering in a commercially relevant lithium ion battery positive electrode,... -
Simultaneous Microwave Dielectric Spectroscopy and Neutron Diffraction Measur...
Ammonia has been proposed as a high density chemical energy-storage media, which can be safely and reversible stored within low cost saline halides. Here we propose to extend... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
Towards the development of carbonitrides as novel two-stage regenerable reage...
We are examining a number of cobalt-molybdenum carbonitrides as possible catalysts for reactions that produce nitrogen-containing organic molecules. There is good evidence that... -
One- and multi-magnon excitations in a strong-leg quantum spin ladder
We propose to measure the one- and multi-magnon excitations in the first realization of a S=1/2 quantum spin ladder in the strong-leg regime. Our material, DIMPY, has very well... -
Kinetics of the ordering transition in ice Ih; crystal structure and thermal ...
Below 80 K ordinary water ice (ice Ih) undergoes a phase transition in which the randomly oriented molecules in the crystal adopt an ordered orientation. This ordered form of... -
Temperature driven spin incoherence and criticality in the Luttinger liquid p...
We propose an experiment on the low energy spectrometer LET to study temperature effects on the Luttinger liquid (LL) phase on the spin ladder geometry. The spin ladder material... -
Proton diffusion in lithium imide: a quasi-elastic neutron scattering study
Li_2NH has been recently considered for H_2 storage applications. However, its low-T crystal structure is still controversial, with at least 6 options compatible with the... -
High Temperature Micromechanics Ni-based Superalloys: Creep, Stress Relaxatio...
In this study, in-situ high-temperature loading investigations will be performed to characterise the micromechanics of a high strength alloy 720Li, during stress relaxation in... -
Pd, Ni, V, Nb and Ti capping layer clamping effects in hydrogen cycling in Ca...
We ask for 8 days of beam time on CRISP to study the absorption and desorption of hydrogen and deuterium in Ti/Mg/Pd trilayer samples. Our specific objective is to understand in... -
The hypersensitivity of the water phase diagram to ammonium fluoride doping
Water displays a highly complex phase diagram that is key to a range of critical processes, from the evolution of icy moons to that of the Earth's hydrosphere and even of life... -
Time Resolved Studies on Inorganic Film Formation at the Air-Solution Interface
In a recent SURF experiment on the formation of silica films templated with cat-anionic/polymer complexes we found that the film growth and evolution occurs on a faster time... -
The high temperature high pressure behaviour of ammonia hydrates
Ammonia hydrates are important constituents of the outer solar system. In recent x-ray studies we have found evidence for a solid solution between ice and ammonia at high... -
In-situ high resolution neutron diffraction studies of cemented carbides
Cemented carbides are composite materials manufactured via powder metallurgy. The excellent wear resistance, high hardness, and high toughness make them widely used materials in... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen...
