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Exploring the Magnetic Behaviour of New S = 1/2 Vanadium Oxyfluoride Kagome A...
Quantum spin liquid (QSL) states emerge when the arrangement of magnetic moments in a material frustrates magnetic interactions and low spin magnetic moments allow for strong... -
Structure, thermal expansion and vibrational properties of ammonium bicarbona...
Ammonium carbonates, sensu lato, have relevance to carbon capture schemes and as potential hydrogen storage materials. These compounds occur on Earth as minerals and, since... -
Investigating the diffusion of cyclic oximes in hierarchically-porous catalys...
Caprolactam (CL) is a high-value chemical precursor to nylon-6. On an industrial scale an aggressive liquid-acid catalyst is used to transform C6-oxime to CL. Due to... -
Low temperature studies of antiferroelectric, PbZrO3
Antiferroelectric materials are attracting extensive attention as potential energy storage devices with higher capacities and lower losses that either piezoelectric and... -
Crystal and magnetic structures of new ruthenate perovskites
Ruthenate perovskites have a diverse range of electronic properties originating from electron-electron correlations within broad 4d bands. We have recently investigated the high... -
Dynamics of PDMS-g-PDMS bottlebrush polymers
Bottlebrush polymers, backbone with long side chains, are very interesting regarding their architecture, which is different from well known linear polymers. Not only the... -
Investigations of amorphous pharmaceutical materials produced from different ...
Pharmaceuticals are usually formulated in the crystalline state for obvious reasons of stability. They may also exist in a disordered and less cohesive state i.e. amorphous... -
The application of INS to characterise iron based Fischer-Tropsch catalysts a...
In conjunction with an industrial partner (Sasol), the applicants have previously used INS measurements performed on the MAPS spectrometer to characterise a series of iron based... -
Diffusion studies using methane as a probe molecule to investigate the methan...
Methanol-to-Hydrocarbons (MTH) is an important industrial reaction. It is thought to work through a 'hydrocarbon pool' mechanism where the hydrocarbons retained within the... -
Pressure-dependent powder neutron diffraction of the p-orbital molecular magn...
The mixed-valence sesquioxides A4O6 (A = alkali metal) are particularly intriguing molecular materials comprising of non-magnetic (O2)2- and magnetic (O2)- anions. Our recent... -
QENS studies of molecular hydrogen in K-doped electrospun graphite nanofibres
The physisorptive capability of graphite-based nanomaterials for hydrogen is strongly dependent on their surface areas and nanomorphologies. We have made electrospun graphite... -
High Pressure Driven Spin States in LaCoO3
This proposal is concerned with determining variations in the high pressure structure of LaCoO3 and observing changes within this as the material undergoes some well... -
Topochemically Reduced Complex Iridium Oxides
In recent years there has been a growing interest in modifying the anion lattice of complex transition metal oxides, via topochemical manipulation, to tune the magnetic and... -
Investigating the diffusion of liquids within the MFI zeolite ZSM-5
The properties of liquids confined in zeolites will be studied by quasi-elastic neutron scattering. Alongside the data previously acquired using quasi-elastic neutron scattering... -
Long-range magnetism in spin, charge, and orbital ordered Pb3Mn7O15
Manganese oxides have attracted great interest in solid-state physics research owing to the diverse range of electronic ordering phenomena. Pb3Mn7O15 is a relatively... -
Hydrogen dynamics in clay nanotubes
We will study H2 dynamics in the nanotubular clay imogolite whose structure has an external diameter of ~2.5 nm and an inner diameter of <1 nm. The tube length of synthetic... -
Dynamics and Phase Transitions in Catanionic Vesicles
The catanionic vesicles are unilamellar or multilamellar spheroid structure composed of cationic and anionic surfactant molecules assembled into bilayers. Vesicles forms by... -
Unexplored Negative Thermal Expansion of Complex Metal Oxides that Exhibit Co...
Negative thermal expansion (NTE), the phenomenon of a material contracting upon heating, is a relatively unique occurrence with practical applications and fundamental structure... -
Verification of extended inverse Dzyloshinskii-Moriya mechanism by comparison...
We propose to perform neutron diffraction experiments on single crystals, 3R-AgFeO2 and 2H-AgFeO2 on WISH. Recently, we have studied magnetic orderings and ferroelectricity of... -
Unravelling Structural Complexity within a Family of Frustrated S = ½ Kagome ...
Quantum spin liquids (QSLs) are exotic states of matter in which magnetic frustration and strong quantum fluctuations destroy long-range magnetic order. Here, we propose to...