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High pressure structural studies of halogen bonded systems
We propose a high-pressure neutron powder diffraction study of three halogen-bonded complexes, namely trimethylamine:ICl, 1,4-dioxane:(IBr)2 and pyridine:IBr. These are some of... -
Magnetic Excitations of a Model Quantum Spin Ladder
(C5H12N)2CuBr4 is the best realisation found to date of an antiferromagnetic quantum spin ladder in the strong coupling limit. This system displays an extremely rich phase... -
Investigation into the Effect of Heating Rates on Recrystallisation Mechanism...
Electrical steels (ES) used in motors and transformers. The major challenge is to optimise themagnetic property of ES to reduce energy waste during service. The crystallographic... -
Spatial, Chemical, and Temporal Resolution of Platinum-Catalysed Benzene Conv...
This proposal aims to study the potential for neutron diffraction to offer spatially-, chemically-, and temporally-resolved information on a dynamic system, in this case the... -
Dy3Mg2Sb3O14 - a 2D Kagome lattice with Classical Ising Spins
Dy3Mg2Sb3O14 forms a layered structure with magnetic Dy3+ ions forming sheets of corner sharing triangles, called a Kagome lattice. The Ising magnetic moments are constrained to... -
Phase Separation in NaTaO3. Can it be controlled by pressure?
The present proposal seeks to establish the pressure dependence of the Pbnm-Cmcm transition in NaTaO3 and some doped variants thereof. It aims to understand the understand the... -
Investigating the role of Oxygen in the delafossite-spinel transformations in...
CuFe1-xCrO2 has potential applications as an SOFC cathode material. It exhibits and interesting transformation on oxidation. This is a follow on from our recent HRPD experiment... -
The possibility of strongly ferromagnetic austenite in a stainless steel
It is generally accepted that austenitic steels (fcc) show no ferromagnetic signature. However, thermomagnetic measurements suggest an unexpected ferromagnetic transition (Tc =... -
An exploration of the vibrational properties of energetic materials using Ine...
We have initiated a new research programme that seeks to correlate features of the crystal structures of energetic materials (explosives, propellants) with their sensitivities... -
Sensing Sulphur Dioxide in Robust Porous MOF Materials via Simultaneous Micro...
We seek to develop new materials for sensing and removal of toxic gases (esp., SO2) and request 2 days on POLARIS to study the structural binding details and dielectric data... -
Is cloud water nitrate radical chemistry important in oxidising thin films on...
Projected climate change is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects droplet size and reflectivity, important climatic effects.... -
In Situ Study of Excess Lithium Metal Oxides Under Charge and Discharge
The next generations of Lithium batteries require materials with an enhanced energy density. The most realistic choice for such systems are the lithium rich electrodes (e.g.... -
Arctic Cloud Chemistry: Can the Halogen "explosion" oxidize material at air-w...
The Arctic climate is strongly influenced by clouds. The oxidative processing of pollutants in Arctic clouds affects droplet size and optical properties, important climatic... -
Cs mixed cation lead perovskites
Organic-inorganic hybrid halide perovskites combine the optoelectronic properties commonly associated with high performance semiconductors with materials synthesis or processing... -
Zero field splitting and quasiparticle breakdown in the two-dimensional quant...
In our recent NRSE experiment on the quasi two-dimensional quantum spin liquid PHCC at TRISP at FRM-II, we have found a zero field splitting (ZFS) of the magnon line of about 50... -
Ammonia synthesis using lithium hydride-metal nitride composites: an in situ ...
The development of more active catalysts for the production of ammonia will have a worldwide impact on the energy cost of producing fertiliser. Composites of lithium hydride and... -
In situ diffraction studies of cathode materials for Li ion batteries
Li-ion batteries are interesting because they offer high power and, as a consequence, they are preferred to aqueous-based batteries for traction applications e.g. hybrid... -
High pressure polymorphism in ammonium bicarbonate, (ND4)DCO3
In an earlier high-pressure survey of the P,T phase diagram of deuterated ammonium carbonate, we observed changes in the neutron powder diffraction patterns that are consistent... -
Ammonia adsorption studies of Li(11)BD4 and Mg((11)BD4)2
On exposure to ammonia, LiBD4 and Mg(BD4)2 form the respective ammoniates, Li(11)BD4(ND3)n and Mg((11)BD4)2(ND3)6. We have identified the decomposition temperatures, kinetics... -
Low energy excitations in solid 4He
The atoms in solid helium are weakly bound and have small mass so that the overlap of their wave functions (zero point motion) is large, making it a quantum solid close to the...
