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YMnO3-x : Mn(I) in a mixed metal oxide ?
Topotactic reduction of YMnO3 with CaH2 yields three new reduced phases. Two of these phases appear to have compositions close to YMnO2.5 but with very different anion vacancy... -
Towards an accurate structural phase diagram for the novel BiScO3-PbTiO3 ferr...
The aim of this experiment is to determine accurately the crystal structures of phases in the (1-x)BiScO3-xPbTiO3 (BST-PT) perovskite phase diagram, particularly in the vicinity... -
Estimating carbon contents within different phases in hypereutectoid steels
Previous studies have attempted to correlate the results of metallography with neutron diffraction studies on the very high-carbon steels used in Oriental blades, and Indian... -
Crystal Structures of Multiferroic MnWO4: HRPD
Multiferroic materials are rare and exceptional: they are ferroelectric and ferromagnetic in the same phase and these two properties can couple. Recently, materials with complex... -
The mechanism of Oxygen Absorption/Desorption in YBaCo4O7+d (Y114) studied by...
An uncommon oxygen absorption/desorption behavior for cobalt oxide YBaCo4O7+d was found[Karppinen et al. Chem Mater 18 2006 490]. Y114 absorbs and desorbs oxygen up to d = 1.5... -
Opening up microemulsion phases in CO2
New types of water-in-CO2 microemulsions using mixed surfactant systems will be investigated by high-pressure SANS (HP-SANS). Exciting new results (see report on RB820030) have... -
Structural study of high pressure phases of multiferroic BiFeO3
BiFeO3 is a rare example of multiferroic material with a simple perovskite-like structure, having extremely large magnetic ordering temperature (TN = 650 K) and Curie... -
Neutron reflection study of effects of non-ionic alkyl ethoxylates on model w...
We propose to use NR to study the structural features of the model wheat wax films formulated from the known main components of long chain primary alcohols and an ester. By... -
Characterising new high-pressure phases of ammonia monohydrate
Over the past two years I have carried out high-pressure surveys of the ammonia monohydrate (AMH) phase diagram using a Paris-Edinburgh press mounted on the D20 beam-line at the... -
Investigation of the phases and chemical composition of early Roman Victoriat...
The proposal involves the non-invasive measurement of ancient Roman coins by ToF diffraction techniques. A well selected series of Victoriati are to be measured in order to... -
Collective dynamics of barium crystal and liquid phases
We propose to measure the inelastic scattering S(Q,E) maps from barium in both the polycrystalline and liquid phases, based on the fact that there are intriguing similarities... -
Structural Studies of PbZr1-xTixO3: completing the puzzle in the tetragonal a...
We request 6 days of HRPD time in order to study the structures on the tetragonal side of the lead zirconate-titanate (PZT) phase diagram, a region that has so far been rather... -
Decomposition studies of Li(1-x)NaxND2, LiNa2(ND2)3 and Li3Na(ND2)4
We ask for 3 days on GEM to study in-situ the decomposition of the Na-substituted LiNH2 phases, Li1-xNaxND2, LiNa2(ND2)3, Li3Na(ND2)4 and their reactions with LiD. LiNH2 is the... -
Recovery and characterisation of high-pressure phases in the systems H2O ¿ NH...
The objective of this experiment is to characterise four particular high-pressure polymorphs of various hydrates discovered by us in recent years during work carried out using... -
Dispersed lamellar phases in dense CO2
This proposal aims to explore these dispersed lamellar phases with a variety of F7H4 derivatives,to help understand their formation in supercritical CO2 (sc-CO2). The focus is... -
Structural determination of non-stoichiomentric phases Li2+yND for 0<y<1
In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of... -
Muon radicals in the metastable phases of Sulphur
Following our investigation of alpha-orthorhombic sulphur, we will measure level crossing spectra of some other allotropes and phases, to find if the muon radical observed in... -
Local structure, dynamics and magnetism of the phases of cobalt imidazolate
This proposal concerns the metal-organic framework (MOF), cobalt imidazolate. Imidazole (im) is a small, flat organic molecule that forms slightly bent metal-im-metal linkages,... -
Search for Antiferromagnetic order in ZrMn2
Today, about seventy years after Laves, there exists a fairly good knowledge about the basic structural principles of Laves phases but many questions still remain. AMn-type... -
Development of internal strains during compression of Al-Si alloy Al-7Si-0.4Mg
This proposal follows on from our successful experiment on ENGIN-X lin 2006, where we measured the development of strains in the aluminium and silicon phases of a common casting...
