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Ion diffusion in sulfide solid electrolytes detected by muon spin rotation/re...
An all solid state lithium ion battery (SSLIB) has an advantage in electrical capacity compared to the popular lithium ion battery (LIB) using a liquid electrolyte. However, a... -
The role of spin fluctuations, disorder and non-colinearity in the INVAR effect
The origin of the Invar effect, whereby certain ferromagnetic alloys exhibit near zero thermal expansion around room temperature is still not properly understood. Although the... -
Exploring local ion diffusion dynamics in hydrated LiRAPs by muSR
Many of the devices currently used for energy storage (e.g., batteries, solar cells) use liquid electrolytes that are known to pose a serious fire and safety risk. In recent... -
Na-Ion Dynamics in the Solid Solution Battery Compound Ca[1-x]Na[x]Cr2O4
Here we propose a u+SR investigation on the solid solution Cax-1NaxCr2O4, a Q1D zigzag chain compound where Na+ ions are allocated in the hexagonal one-dimensional channels... -
Magnetic ordering in the layered oxide arsenide Sr2Cr3As2O3
This experiment will probe the evolution of magnetic ordering in Sr2Cr3As2O3, a compound containing Cr3+ moments in Cr2O square layers and Cr2+ moments in CrO2 layers. We will... -
Hydrogen impurity in solar cell materials CIGS and CZTS
In this proposal we intend to complete the characterization of the hydrogen impurity in solar cell materials Cu2ZnSnS4 (CZTS) and Cu(In,Ga)Se2 (CIGS), by using the positive... -
Investigation of Li diffusion in Li-ion battery materials by muSR
We would like to propose a continuation experiment on Li-ion battery cathode material, Li(Ni,Co)O2. In previous experiments in 2013 and 2014, we attempted muSR technique to... -
Disorder and ion mobility in Li4BH4(NH2)3 and Li2BH4NH2
Hydrogen storage is a significant area of energy materials research and there have been extensive efforts into the discovery and development of lightweight materials. Although... -
Muonium Defect Levels in 4H Silicon Carbide
We propose to obtain the temperature dependence of the diamagnetic spin-precession amplitudes up to 1100 K for the three electrical types of 4H-SiC in order to extract the Mu... -
Li-diffusion dynamics in high voltage fluoride-containing cathodes
Research on positive insertion electrodes for high performance batteries has seen immense interest in fluoride containing compounds, since higher operating potentials can be... -
The role of Ti-doping on hydrogen desorption temperature in LiAlH4 and NaAlH4
Fuel-cell cars are expected to be an ultimate solution for accommodating clean environments with convenient personal transport system. In order to make fuel-cell cars more... -
Muon Investigation of sodium super ionic conductors for sustainable and safe ...
With increasing demands for high performance/capacity rechargeable batteries the materials science community is currently facing two severe issues. First of all there is from a... -
Characterization of Li-diffusion in ordered and disordered cathode materials ...
Lithium-excess cathode materials can deliver high capacity and lead to high energy density. Lithium-excess cathode materials are categorized as ordered and disordered on the... -
Magnetic properties of photomagnetic molecular square complexes
This experiment aims at studying the magnetic behaviour of the molecular square complex {[Fe{B(pz)_4}(CN)_3]_2[Co(bik)_2]_2}(ClO_4)_2 . 3H_2O [B(pz)_4 = tetrapyrazolylborate,... -
Motion of Diamagnetic Muonium Centres in II-IV-V2 Chalcopyrites
We propose to obtain the detailed temperature dependent diffusion characteristics for diamagnetic muonium defect centres, assumed to be a 'bare' muon, in selected members of the... -
Studies of magnetic polaron formation in EuS via RF-µSR
Experiment is proposed to identify magnetic polaron bound to the muon using RF-muSR. In recent experiment at TRIUMF magnetic polaron was found in transverse field and its... -
Carrier density in novel Li ionic conductors studied with muons
When we know an intrinsic diffusion coefficient of Li-ion (D) in an ionic conductor, we could estimate a number of mobile Li ions, i.e. carrier density (n), from ionic... -
Muons for Energy Nanonics
LiFePO4 (LFP) is a commercially applied cathode material for lithium ion batteries. With its Li ion hopping predominantly occurring along one-dimensional channels, LFP is a very... -
Determination of a reaction area of cathode in a liquid electrolyte by muSR
In order to estimate a reliable reaction area (a_r) between cathode and liquid electrolyte in a Li-ion battery, we wish to propose a muSR experiment on a charged-state cathode... -
Li diffusion in Li-Mn-O (continuation)
This proposal describes a continuation muSR experiment on Li-Mn-oxides to see Li diffusion, because muSR is a powerful technique to detect it in the compounds containing...