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IINS measurements on the terminating protons of the basic structural units of...
More than 6 million tonnes of carbon black per year are produced worldwide. The major part is used as reinforcing filler material in tyres and mechanical rubber goods. For... -
Characterisation of Pearlman's catalyst
Pearlman¿s catalyst is commonly used in various hydrogenation, arylation and O-debenzyaltion reactions. The catalyst is unusual that it is active but not pyrophoric. It is... -
The adsorption of methyl proprionate on silica catalysts.
Commercial routes for the manufacture of methyl methacrylate monomer have recently been developed that involve the reaction of esters over modified silicas, which are amphoteric... -
Metastable Water Ice and Nitric Acid ¿ observing the phase changes
The IPCC report 2007 underlines the particular importance of aerosol particles for the water cycle and the radiation balance, and thus for the global climate. In Cirrus clouds... -
Local structure and proton sites in proton conducting brownmillerites
This proposal requests 3 days on Maps to investigate the nature of local structure and proton sites in the proton conducting brownmillerite system Ba2In1.85M0.15O6H2 (M = In,... -
The use of INS to investigate reactions relevant to Fischer-Tropsch catalysis
In collaboration with an industrial partner, the PI is seeking to use INS to help characterise a series of catalysts active for the important Fischer-Tropsch (F-T) process. As... -
Influence of promoting additives on the formation of palladium hydrides in te...
Steering and optimizing catalyst selectivity at ¿ simultaneously - adequate catalyst activity is a continuing challenge in chemical technology and of high economic impact. In... -
The pressure response of the new superconductor LiFeAs
We will probe the response of the 18K superconductor LiFeAa to pressures of up to 2 GPa in order to investigate the evolution of the crystal structure. In particular we wish to... -
Correlation of structures, compositions and magnetism of copper-deficient lay...
This is part of a larger experiment which will investigate three related systems which contain copper deficient anti-fluorite-type copper sulfide layers. The overall aim is to... -
Investigation of the intermolecular dynamics of polycrystalline C60
Recent work by the proposers on modelling the coherent inelastic neutron scattering spectrum for polycrystalline samples of the two phases of this material has shown that all of... -
The first in operando INS study of a catalytic reaction: CO oxidation over PdO
Inelastic neutron scattering has been used to study adsorbed species on catalysts for more than 30 years. All of this work has one feature in common: they are all ¿snapshots¿ of... -
Understanding the mechanism of benzyl alcohol oxidation using supported Au-Pd...
Gold, in its nano-scale, has been found to be very effective catalyst for oxidation reactions. More recently, it was shown that supported Au-Pd catalysts can be used for... -
Characterisation of the hydrides in Stryker¿s reagent
In recent years, soluble derivatives of CuH prepared by non-aqueous routes have become important as mild reducing agents, one such compound, Stryker¿s reagent [Ph3PCuI]6. The... -
Copy of: IINS Study of the Molecular Properties of Hydrogen Peroxide/Water Mi...
Hydrogen Peroxide is one of the cleanest, most versatile strategic base chemicals available. It is used at the large scale as oxidising agent in the chemical industry, as a... -
Simultaneous Raman and INS Studies of C70
The vibrational spectrum of C70 has been investigated by many techniques since it became available in significcant quantities. Previous INS spectra were recorded with small... -
An INS Study of the Effect of Pressure on the Crystal Structure Titanium Tetr...
At ambient pressure TiCl4 forms a molecular solid consisting of isolated TiCl4 molecules (phase-I). At 0.5 GPa this structure undergoes a transition to phase-II, which is... -
Structures of LiFeP and the solid solution LiFeAs1-xPx
In this experiment we will determine the detailed structure of the 6 K superconductor LiFeP and phases close in composition which are iron rich: Li1-xFe1+xP. This will enable... -
Structures and magnetism of iron arsenide superconductors with widely separat...
The recent discovery of superconductivity in a series of iron pnictide materials has provided impetus to the field of new materials discovery. Like in the cuprate... -
Can INS measurements access hydrocarbonaceous overlayers on heterogeneous hyd...
This application seeks to discover whether the catalyst handling protocols refined for INS measurements of a variety of heterogeneous catalytic systems can be further exploited... -
Inelastic Neutron Scattering Investigations of Hydration Layers on Cobalt Oxi...
We propose to collect INS data with TOSCA on nanoparticles of CoO and Co3O4 with different levels of hydration and size to study the effect of these parameters on the heat...
