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The application of INS to examine high specification Fe Fischer-Tropsch catal...
Over the last 4-5 years the research team have been developing INS methodology that can be applied to investigate Fe Fischer-Tropsch (F-T) catalysts. The first stage of that... -
Can we use the H-H stretch of adsorbed dihydrogen to characterise materials?
The use of the J 0-to-1 rotational transition of dihydrogen has been extensively used to characterise the state if hydrogen in and on materials. The disadvantage of studying the... -
Does the methyl group of adsorbed methoxy on eta-alumina tunnel?
This application seeks to discover whether it is possible to observe the tunnelling of the methyl groups of adsorbed methoxy on eta-alumina. To our knowledge, this is the first... -
Characterisation of tunnelling modes of adsorbed methoxy on eta-alumina
Our previous proposal strongly suggested that the methyl groups of adsorbed methoxy on eta-alumina do exhibit tunnelling. This application aims to provide additional evidence to... -
Probing the products of free radical reactions in ionic liquids
Many room temperature ionic liquids (salts with melting points near room temperature that hereafter will be referred to as ionic liquids) are ¿green solvents¿ for chemical... -
Observation of intermediates on a transfer hydrogenation catalyst
The design and development of novel catalysts for chemical synthesis is incredibly important from both academic and industrial perspectives. Approximately 90 % of all commercial... -
Solvation and interaction of polymers showing lower critical solution tempera...
LCST, or ¿cloud point¿ is a property of some types of polymers in solution. At low temperatures, the polymers are fully solvated and exist as extended conformations in solution.... -
Proton dynamics of supported palladium/gold entities in technical catalysts f...
Vinyl acetate is used on the million tonnes per year scale for the production of various grades of polyvinyl acetate, a component in paper, adhesive and textile applications.... -
Probing the binding of CO2 on supported aminosilane sorbents with INS
Fossil fuels are the main contributor to global energy consumption, which has increased the amount of atmospheric CO2, increasing the severity of climate change and health... -
Neutron spectroscopy study of the C-H vibrational modes in defective graphene
We have conducted an extended study of hydrogenated defective graphene, synthesized by chemical routes (hydrogenated thermal exfoliated graphite oxide or H-TEGO), including... -
Microscopic structure of acetic acid in water and methanol
Some of the most important chemical reactions involve Brønsted acids and bases where the solvation structure and transport dynamics of charged defects in hydrogen-bonded... -
Higher resolution inspection of the hydrocarbon pool connected with the metha...
The reaction of methanol to form hydrocarbons over zeolite catalysts is an important option for conversion of natural gas or coal to liquid fuels. We have shown previously via... -
MAPS commissioning (short)
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µSR studies of free radical reactions by non-thermal microwave effects
We plan to study the non-thermal microwave (MW) effects on H2O2 through its reaction with muonium under MW irradiation. The key objectives are 1) for the first time definitively... -
INS study of the first carbon-carbon bond formation stage in the methanol-to-...
Methanol-to-Hydrocarbons is an industrially relevant reaction. The generally accepted mechanism under steady state is the 'hydrocarbon pool' mechanism with the hydrocarbons... -
Determination of the structure of methoxy on eta-alumina
We have recently demonstrated that we are able to obtain structural information about adsorbed hydrogenous species from a variety of metal catalysts. We emphasise that this is a... -
Methanol and ethanol analysis of sediment core AT18-2_13
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Geochemistry of two sediment cores and a reference site from the Orca Basin, ...
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Depth profile of methanol in site D2 and site D6 in the northwest Pacific Oce...
We investigated the seawater methanol abundance in the northwest Pacific Ocean (NWPO) area. Seawater samples were collected during May-June 2021 aboard the R/V “Dongfanghong 3”... -
Volatile organic compounds (VOC) at time series station Wollongong, 2012-12-2...
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