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Thermal expansion and simultaneous Raman spectroscopy of methanol ammoniates,...
We have recently determined the structures of methanol-monoammoniate, and Me-hemiammoniate from neutron powder data. These are found to have different degrees of C-H...O... -
Does elastic twinning play a role in the thermal expansion behaviour of polyc...
We request two days of beam-time on POLARIS to obtain high resolution measurements of the thermal expansion of dolomite [CaMg(CO3)2]. The experiment forms part of a larger... -
Dynamics of PDMS-g-PDMS bottlebrush polymers
Bottlebrush polymers, backbone with long side chains, are very interesting regarding their architecture, which is different from well known linear polymers. Not only the... -
Neutron scattering and muSR studies of magnetic phenomena in YFe2Al10: case s...
In strongly correlated electron systems, the proximity to magnetic ordering has been of special interest. Magnetism in this class of systems is often suppressed by the Kondo... -
Lyso Cooling Ref
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Phase Separation in NaTaO3. Can it be controlled by pressure?
The present proposal seeks to establish the pressure dependence of the Pbnm-Cmcm transition in NaTaO3 and some doped variants thereof. It aims to understand the understand the... -
Topotactically reduced phases containing square planar Co(II) centres
The topotactic reduction of Sr3Co2O5Cl2 and Sr3Co2O5.80 yields the Co(II) phases Sr3Co2O4Cl2 and Sr3Co2O5 respectively. These phases contain corner linked arrays of... -
Diffusion studies using methane as a probe molecule to investigate the methan...
Methanol-to-Hydrocarbons (MTH) is an important industrial reaction. It is thought to work through a 'hydrocarbon pool' mechanism where the hydrocarbons retained within the... -
Spin excitations in Rb0.8Fe1.7Se2-xTex with Tc=20K
The alkaline iron selenide RbFe1.6+xSe2 superconductors are a new system of iron-based superconductor with Tc up to 32K. According to recent experimental results, the... -
Programme Access Rosseinsky/Claridge
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Test of FERNS CCR at low temperatures on MERLIN
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Cs mixed cation lead perovskites
Organic-inorganic hybrid halide perovskites combine the optoelectronic properties commonly associated with high performance semiconductors with materials synthesis or processing... -
The high-pressure structures of carbon dioxide hydrate
The gas hydrates offer potential as hydrogen and carbon dioxide storage materials for use either in transport applications or for carbon sequestration. We have discovered a... -
Micropore Collapse in Bulk Amorphous Solid Water
We propose to study the influence of deposition rates and annealing effects on microporous amorphous solid water samples (ASW) using NIMROD. The data will allow us to monitor... -
Decoupling effect between protein and water
Water plays a critical role in life. A hydration level, h ~ 0.2 g water/g protein, is found to be the minimum for the dynamical transition in protein at Td ~ 200 K. This... -
Studying dynamics of water on graphene by quasi-elastic neutron scattering
Graphene-based materials have unique structural and physiochemical properties, and have been exhibited as efficient working substances to filter salts in saline water.... -
Exploring cation dynamics in a hybrid Prussian blue analogue
Many hybrid Prussian blue analogues show exploitable electric behaviour, such as piezo-, pyro-, or ferroelectricity or dielectric switching. We have previously characterised one... -
Structural studies of the cycling and decomposition of Mg(NH3)6(BH4)2
Given its high hydrogen gravimetric density, ammonia may be utilised as a hydrogen carrier, and thus ammonia stores are an area of interest. It is known that Mg(BH4)2 takes up... -
High energy dependence of countable spin excitations in CaFe2O4 using backsca...
Recent high resolution spectroscopy has found countable and discrete excitations in the two dimensional magnet CaFe2O4. This work aims to track these excitations to higher... -
Hydrogen dynamics in a series of metal borohydride ammonia inclusion compound...
The proposed quasi elastic neutron scattering experiment at ISIS aims at the characterization of the dynamical properties of the series of coordination complexes Pr(BH4)3·nNH3,...
