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The high temperature high pressure behaviour of ammonia hydrates
Ammonia hydrates are important constituents of the outer solar system. In recent x-ray studies we have found evidence for a solid solution between ice and ammonia at high... -
Investigating the internal structure of thermally annealed two-component poly...
The elucidation of the compositional profile of polymer:small molecule nanoparticle films is critical for applications such as water processable organic solar cells. In order to... -
In-situ high resolution neutron diffraction studies of cemented carbides
Cemented carbides are composite materials manufactured via powder metallurgy. The excellent wear resistance, high hardness, and high toughness make them widely used materials in... -
Neutron Total Scattering of Crystalline Materials in the Gigapascal Regime
Over the past few years, extensive developments have been made in the use of neutron diffraction for structural studies of liquids and amorphous materials at high pressure.... -
In situ studies of mixed-phase oxygen transport membranes
The oxygen transport membrane is a system being developed by St Andrews in conjunction with industry, which at high temperatures will allow the selective migration of oxygen... -
High-pressure powder neutron diffraction study in Pd2MnIn
Intermetallic ternary full Heuslers have potential spintronic applications, due to a possible link between the mechanisms for magnetism and half-metallicity in these systems.... -
In-situ Neutron Diffraction Studies of Lithium Battery Materials
This proposal seeks to test a new battery designed to allow in situ neutron diffraction measurements of lithium ion battery electrodes under charge and discharge. We have... -
Towards the development of lithium manganese nitride as novel two stage regen...
In the last decades the production and consumption of reactive nitrogen increased exponentially due to the extensive utilisation of nitrogen containing compounds as fertilizers... -
Investigation of maleic-d2 acid isomerization at high pressure
Experiments performed in our laboratory indicate that maleic acid undergoes an unexpected structural change when subject to high pressure and temperature conditions. For these... -
Gas-phase oxidation of insoluble monolayer at air-water interface with no equ...
The Earth¿s climate is strongly influenced by clouds. The oxidative processing of pollutants in clouds affects cloud droplet size and optical properties, important climatic... -
Investigation of the pressure dependence of the negative area expansion mater...
We will investigate the structure of 4-chloroimidazole a material, which undergoes extreme anisotropic thermal expansion,.as a function of pressure at a range of temperatures... -
In-situ studies of alkaline earth nitride deuterides
Heavy alkaline earth nitride hydrides (AE2NH, with AE = Ca and Ba) are of interest due to their potential suitability as electrolyte materials in a variety of electrochemical... -
Micelle structures in unequal mixtures of amino-acid surfactants
In a previous proposal we started to study the micellar structures formed from biodegradable surfactants synthesised using amino acids as the headgroups. The aim of this work is... -
Structures of metastable water ice XVII with different guests molecules
Very recently, we have studied the crystalline structure of the C0-phase H2-filled ice (recovered at room pressure and low temperature) and ice XVII, a new form of ice... -
Structural determination of non-stoichiomentric phases Li2+yND for 0<y<1
In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of... -
Wetting Transitions of Tackifiers in Adhesives
Migration and surface segregation of low molecular weight oligomers in adhesive formulations is a poorly understood, but hugely important phenomenon, responsible for most of the... -
The chemisorption of hydrogen over a high surface area cobalt catalyst: An IN...
In collaboration with Sasol Technology UK Ltd, the research team have previously used INS to investigate the surface chemistry of synthesis gas (CO + H2) over a series of... -
Investigating the formation of novel mixed amide-imide complexes and understa...
Inexpensive light-metal amides are among the most highly active and effective ammonia decomposition catalysts at modest temperatures and are likely to surpass the performance of... -
Monitoring Gamma Prime Evolution in Superalloys using Small Angle Neutron Sca...
The aim of the experiment is to monitor the temporal evolution of gamma prime precipitates in three polycrystalline nickel base superalloys using Sans2D. This instrument is... -
Stroboscopic Neutron and X-ray mapping of strain fields in dynamically loaded...
Bearings are essential components in many types of machinery, working to reduce energy losses. Over the last century improved analytical models were developed for predicting the...