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Continued studies of materials in the BiFeO3-KNbO3 solid solution
In recent years there has been a resurgence in research dedicated to ferroelectric materials primarily due to the combination of the requirement for Pb-free replacements for... -
4f electronic states of the filled skutterudite compound PrFe4Sb12 synthesize...
Crystals of the filled skutterudite PrFe4Sb12 with the 73~87% Pr-site filling fractions prepared under ambient pressure show some magnetic ordering around 5 K and their... -
Chasing the symmetry of the BiFeO3 γ-phase in the isostructural A- and B...
BiFeO3 is by far the most widely studied multiferroic material and yet many mysteries remain in the phase diagram. One mystery is the crystal structure of the high T gamma... -
Towards an improved understanding of the active phase of iron based Fischer-T...
The applicants have recently completed a series of INS studies on a model iron Fischer-Tropsch catalyst. That work established that different sample pre-treatments could... -
Interplay between the spin dimer and the triangular lattice in the 6H-perovsk...
The recently discovered 6H-perovskite Ba3PrRu2O9 is comprised of the triangular layers formed by Pr4+ ions and the Ru2O9 dimer units located between the triangular layers. Three... -
Environmental Apatites
Materials adopting the apatite structure are gaining an increasing importance as potential solid-oxide fuel cell electrolytes and for the chemical stabilisation of high level... -
The relationship between the pseudogap and magnetic excitations in La2-xSrxCuO4
This proposal is part of an ongoing project to relate the magnetic excitations to other electronic properties of the cuprate superconductors. We have recently proposed that the... -
Variable temperature structural study of oxides with low thermal conductivity
The aim of the experiment is to investigate the temperature evolution of the crystal structure for two transition metal oxides with low lattice thermal conductivities. This will... -
The Metal to Insulator Transition (MIT) in Bi1.7V8O16 probed with neutron spe...
We propose to investigate the low energy spin and orbital fluctuations in Bi1.7V8O16 which displays a metal to insulator transition. This work will be performed in conjunction... -
Structure Sequence in Ca(1-x)Nd2x/3TiO3 Ceramics
Microwave dielectric ceramics are used in communications devices. Such materials need high relative permittivity, high dielectric quality factor and be temperature stable.... -
Study of vibron quasibound state in RAg1-xCuxAl3, 0<x<1 (R=Ce and La) through...
We propouse the study of crystal-field or vibron excitations along the series RAgxCu1-xAl3 (R=Ce and La, 0 -
Structure of Molecular Hydrogen in High Charge Pillared Clays
In this proposal we aim to study low temperature structure of hydrogen in the interlayer region of partially hydrated pillared clays. There are linked dual motivations for this... -
Characterisation of Precious Metal Hydrous Oxide and Hydroxide Compounds
Approved proposal under the ICRD Scheme Proposal ICRD0003 -
Investigation of ambient temperature polarity and magnetism in the ternary so...
Pb-based materials such as PbZrxTi1-xO3 (PZT) are widely used as transducers, actuators and sensors in a range of modern technologies due to their excellent piezoelectric and... -
Sensing SO2 in Robust Porous MOF Materials via Simultaneous Microwave Dielect...
We seek to develop new MOFs for sensing and removal of toxic gases (e.g., SO2) and request 4 days on POLARIS to study the structural binding details and dielectric data... -
The Active Site in Iron Molybdate Catalysts for Selective Methanol Oxidation
Formaldehyde is an industrially important chemical (world production 32 million tonnes in 2006) currently made from methanol using an iron molybdate catalyst. Reaction occurs at... -
How does a catalyst promoter affect the degree of hydrogen retention of iron-...
We have recently used INS to determine how a hydrogen pre-treatment stage of an iron based Fischer-Tropsch catalyst may modify catalytic performance. That work established how... -
Neutron Total Scattering Investigation of Temperature Driven Transitions in L...
This proposal is concerned with determining the local structure of LaCoO3 and observing changes within this as the material undergoes some well characterised temperature driven... -
Simltaneous dielectric spectroscopy and neutron diffraction
We have constructed a novel microwave frequency resonator that can sit within the GEM and POLARIS diffractometers and will allow us to simultaneously collect diffraction and... -
Formation and ammonia decomposition behaviour of lithium nitride hydride
Ammonia is seen as a key part of the transition to a sustainable energy economy, but needs decomposition catalysts to release its stored hydrogen. Lithium nitride-hydride...
