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Programme Access Rosseinsky
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Investigation of maleic-d2 acid isomerization at high pressure
Experiments performed in our laboratory indicate that maleic acid undergoes an unexpected structural change when subject to high pressure and temperature conditions. For these... -
Development of a Novel Low - Intermediate Temperature Solid Proton Conductor
The compound, Si5O(PO4)6, is a component of a solid phosphoric acid catalyst, it has highly unusual coordination of the silicon (octahedral, as well as the more common... -
A neutron diffraction study of Li2xMn1-xPS3 films
In this experiment we propose to perform neutron diffraction measurements on lithium intercalation compounds,Li2xMn1-xPS3,at room temperature,40ºC,75 ºC,150ºC and under vacuum... -
Local Structure in (K,Na)NbO3 Piezoelectric Ceramics
KxNa1-xNbO3 (KNN)-based solid solutions are promising lead-free piezoelectrics for ceramic actuators. In this system, the long-range order of octahedral rotations and... -
Copy of: Local magnetic order and the paramagnetic-parmagnetic transition in MnO
The antiferromagnetic-paramagnetic transition in MnO at 118 K occurs at a much lower temperature than anticipated from its Curie-Weiss constant theta~550 K. Consequently, strong... -
Oxide ion vacancy distribution in A site substituted defect pyrochlores.
Electrolytes based on pyrochlores such as Ln2M2O7 (M = Ti, Zr, Hf) have attracted attention due to their relative stability combined with relatively high ionic conductivity at... -
Muonium in alpha-boron
Previous muon experiments have identified a muonium state in the commonly occuring, but complex, beta rhombohedral form of elemental boron. To complement recent theoretical work... -
QENS studies of hydride ion diffusion in alkaline earth hydrides
We propose to study hydride ion diffusion in AEH2 (AE = Ca and Ba) using the QENS technique. We have recently demonstrated that the charge carrier in these materials are hydride... -
Structural determination of non-stoichiomentric phases Li2+yND for 0<y<1
In a series of in situ neutron diffraction measurements from deuterium up-take in Li3N, the present authors have identified a novel non-stoichiometric 'quasi-imide' of... -
Programme Access Rosseinsky/Claridge
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Understanding composition-driven anomalous tetragonality in a ferroelectric s...
The primary aim of this proposal to investigate a series of newly discovered Bi- containing ferroelectric systems based on Bi(MeMe)O3-PbTiO3 perovskite through studying their... -
Ordering phenomena and magnetic phase transitions in Mn2TeO6
Our aim is to study with high resolution neutron powder diffraction the two orthorhombic phases of Mn2TeO6 at RT, so as to understand the origin of the observed structural... -
Structural Changes through the Semiconductor to Metal Transition in Cu2ZnGeSe4
We wish to collect powder neutron diffraction data as a function of temperature to investigate structural changes through a phase transition in the parent thermoelectric phase... -
Elemental Boron synthesized in supercritical metallic solvents at high pressu...
Our recent high (P,T) developments at PEARL beamline will allow us to study the kinetic and thermodynamic behavior of boron 11B under pressures up to 12 GPa and temperatures up... -
Effects of Local Displacements on Phase Transitions in Sr- and Ca-substituted...
Ferroelectric BaTiO3 (BT) constitutes a base system for many practical applications ranging from classical capacitors to tunable dielectrics. A dielectric response in BT is... -
Investigation of single crystal diamond detectors at high temperature under i...
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In Situ Structural Study of Low Temperature Synthesised TiP2O7
The AX2O7 series has received much recent attention due to its ability to host a wide range of 4+ cations. The members of this series have been shown to exhibit complex... -
Mass-selective Neutron Spectroscopy of Molten FLiBe
We request time on VESUVIO to study the properties of FLiBe using mass-resolved neutron spectroscopy (MANSE). FLiBe is a mixture of BeF2 and LiF and its physical properties in... -
The topotactic reduction and anion exchange of complex oxy-halides
The reaction of LiH with the oxy-chloride Sr3Fe2O5Cl2 initially leads to the topotactic deintercalation of oxide ions and the formation of Sr3Fe2O4Cl2 containing sheets of...
