A neutron diffraction study of Li2xMn1-xPS3 films

DOI

In this experiment we propose to perform neutron diffraction measurements on lithium intercalation compounds,Li2xMn1-xPS3,at room temperature,40ºC,75 ºC,150ºC and under vacuum (pressure of about 10-4torr).The samples are crystalline films casted on aluminum substrates.We would like to obtain information about the Li+ atomic environment (where the solvated Li+ ions are) and how the Li ions behave when temperature changes and/or when films are under vacuum condition.These informations are essential to understand the role of the Li+ ions in the dielectric response of these films. Since Li is a poor x-ray scatterer little informations are known about the detailed structural features of the Li2xMn1-xPS3 films:only the basal spacing is reported in the literature at different temperatures during a dehydration/rehydration cycle.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24088168
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24088168
Provenance
Creator Dr Gabriele Salvato; Dr Francesco Grazzi; Professor Dame Letteria Silipigni; Dr Lilla Schirò
Publisher ISIS Neutron and Muon Source
Publication Year 2014
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2011-10-24T08:28:01Z
Temporal Coverage End 2011-11-22T09:56:30Z