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Probing the catalytic mechanism of CO2 utilisation for cyclic carbonate synth...
The rapidly increasing atmospheric concentration of carbon dioxide necessitates the development of novel technologies for sustainable carbon capture and utilisation procedures.... -
Practical viscosifiers for supercritical CO2
This proposal explores headgroup-free, fluorocarbon-hydrocarbon hybrid compounds able toform viscous elongated aggregates in supercritical CO2 with the aim of improving... -
Total Neutron Scattering Measurements of Supercritical CO2 Injection in Carbo...
Carbon dioxide is a commonly used fluid in Enhanced Oil Recovery (EOR). CO2 EOR process can contribute to the minimisation of the impact of greenhouse gas emission by keeping... -
Dispersed lamellar phases in dense CO2
This proposal aims to explore these dispersed lamellar phases with a variety of F7H4 derivatives,to help understand their formation in supercritical CO2 (sc-CO2). The focus is... -
New surfactants forming anisotropic micelles and microemulsions in CO2
An analogue of the popular surfactant AOT with isopropyl glycol tails (IG-AOT, Figure.1) has been recently designed as a co-surfactant for water-in-CO2 (w/c) systems: stable... -
Probing high-density confined CO2 in ultra-microporous carbon
Sequestration of carbon dioxide in natural and engineered porous materials is most viable option to mitigate the anthropogenic CO2. However, the fundamental understanding of... -
Structure of hot dense liquid carbon dioxide
We propose to study the structure of liquid CO2 by neutron diffraction under high pressure and high temperatures to 6 GPa / 800 K. Carbon dioxide belongs to the most fundamental... -
INS Study of Cu-based methanol synthesis catalysts
In low-pressure methanol synthesis from fossil synthesis gas, Cu/ZnO/Al2O3-catalysts are successfully used in industrial synthesis at 250°C and 50-100 bar, but the exact... -
Study of structural and phase transitions of carbon dioxide confined in the n...
When fluids are confined in pores with dimensions in the nanoscale, their properties differ from the bulk mainly due to the solid-fluid interactions and the finite pore size.... -
Characterization of heterogeneous solvent structure in a carbon capture fluid
We propose to use neutron scattering experiments to gain molecular level insight into an intriguing liquid structure observed in a water-free CO2-capture solvent. Switchable... -
Nonfluorous Cosurfactant/Hyperbranched Surfactant Mixtures for W/CO2 Microemu...
This proposal aims to explore cheap and environmental-benign cosurfactants (or cosolvents) for yielding CO2-philic hydrocarbon surfactant/water/CO2 microemulsions (W/CO2... -
Hydrogen containing intermediates during catalytic CO2 reduction on sulfides
We investigated the influence of sulfur on a well-known methanation catalyst, nickel on alumina/silica, so as to gain more information about sulfur poisoning. By different... -
Probing the binding of CO2 on supported aminosilane sorbents with INS
Amine sorbents are pivotal to carbon capture, and the nature of the amine is shown to affect CO2 binding mechanisms. FT-IR has previously been used to explore the chemistry... -
Exceptionally High Gas Adsorption in a Series of Metal-Organic Frameworks: An...
Porous functional metal-organic framework (MOF) materials show great potential for high capacity gas storage and separation. We seek to develop new materials for carbon capture... -
Graphite Oxide Intercalation: Tailoring Adsorbate Geometry
The search for new porous materials is increasingly driven by a socio-economic pressure to diversify our energy supply and minimize environmental impact. Carbon-based... -
Surfactant ionic liquids as tuneable structured media
This proposal aims to explore aqueous phase structures of a new range of ionic liquid surfactants (IL-surfs). These IL-surfs have interesting potential applications as reaction... -
Highly selective adsorptive SMOFs
In the area of metal-organic porous materials, supramolecular metal-organic frameworks (SMOFs) constitute a blooming alternative. Their examples are still relatively scarce when... -
CO2 foams stabilized by W/CO2 interfacially active hydrocarbon surfactants an...
CO2 foams can be formed in water/carbon dioxide (W/CO2) mixtures with the aid of W/CO2 interfacially active hydrocarbon surfactants and surface treated silica nanoparticles... -
Mixing CO2-philc surfactants and hydrotropes as a new approach to control vis...
One application where liquid CO2 has found success is enhanced oil recovery (CO2-EOR) of crude oil from porous rocks. However, a significant disadvantage of using CO2 in EOR is... -
Concentrated emulsions as proxy CO2 thickeners
The proposal aims to explore the oil-in-water (brine) high internal phase emulsion systems (HIPEs) formed by nonylphenol ethoxylate surfactants using contrast variation SANS...
