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Crystal and magnetic structures of mixed-valent V2OPO4
The electronic states of transition metal oxides usually result from a coupling between the three degrees of freedom: charge, orbital and spin states. When metal-metal distances... -
Test of in-situ thermo-cap for slab cans
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In-situ reaction of lithium amide or imide with manganese(IV) oxide
We request 3 days beam time on POLARIS for in-situ powder diffraction studies of the reactions of lithium amide or lithium imide with manganese(IV) oxide under flowing argon or... -
Fine structure of a confined quantum translator-rotator probed with high-reso...
A process known as molecular surgery enables the synthesis of the fullerene C60 enclosing a small molecule such as H2, H2O, HF and CH4. The caged molecules in these molecular... -
Search for Weyl Magnon in LiGaCr4O8
Weyl magnon in the chromium-based breathing pyrochlores is a recently predicted novel magnetic excitation state. Similar to its anolog, Weyl fermion in the electric systems,... -
Search for structural modulation lifting the orbital degeneracy in triangular...
This proposal is part of our research programme on spin and orbital order in frustrated systems. AgNiO2 has a layered crystal structure with Jahn-Teller active Ni3+ ions forming... -
Incommensurate-commensurate phase transitions in K2SeO4
Materials with incommensurate structures often show exotic properties (such as charge density waves). The development of reliable and efficient refinement techniques for such... -
Ionic mobility in soggy sand electrolytes
Ionic liquids (ILs) are gaining increased interest as electrolytes given their thermal and chemical stability, wide electrochemical windows, and ionic conductivities. However,... -
Investigation of modulated crystal and magnetic structure of Ni-Pt-Mn-Ga ferr...
Ferromagnetic shape memory alloys (FSMAs) are of recent interest because they exhibit a shapememory effect that can be driven by magnetic fields. Thus, FSMAs are important for... -
Rotational dynamics in the ferroelectric and giant barocaloric (NH4)2SO4
Barocaloric materials, in which a large isothermal entropy change is associated with a pressure induced phase transition, offer an alternative to vapour-compression technologies... -
Understanding of Competing Magnetic Processes in La0.7Sr0.3MnxFe1-xO3 Perovskite
The aim of this experiment is to complete the understanding of the complex nature of the structural and magnetic interactions in the La0.7Sr0.3Mn1-xFexO3 series of materials in... -
Deuteration-induced phase transition in a multiferroic framework material
The hybrid organic-inorganic perovskites are of great interest as functional materials, because they combine the well-established perovskite topology with new physics and... -
Magnetism and structure of Mn2FeRuO6
Magnetoelectric materials, combining properties associated with magnetic and ferroelectric memory applications (e.g. in hard drives) are difficult to prepare but would represent... -
Overcoming Chemical Reaction Equilibrium: Determining the Chemical Potential ...
We have developed and demonstrated a novel process to overcome chemical reaction equilibrium constraints on an important reversible industrial chemical reaction by using... -
Quenched salt hydrates new ways of probing water clusters.
Very rapid quenching of liquids to form a glass, from which crystalline phases are subsequently obtained by devitrification, is a powerful technique for obtaining novel... -
Understanding Structural Changes in Amorphous Solid Water (ASW) on Heating
This experiment will establish the structural changes that occur in Amorphous Solid Water (ASW) prior to the process of pore collapse or crystallisation. We will study the... -
Understanding Deep Earth Mineralogy: A High P/T study of CaSiO3 Perovskite
CaSiO3 perovskite is the third most abundant mineral in the Earth's lower mantle; it also occurs as a major phase at lower pressures and temperatures in subduction zones, where,... -
Apatite-type Oxides for Energy Applications: Symmetry Distortion Mode Analysi...
Apatites are a large group of chemically and structurally flexible functional materials with important applications as solid electrolytes. The majority of known apatite... -
The PVT equation of state of D2O ice III / IX
The high-pressure form of solid water, ice III, is the equilibrium phase in contact with liquid water at pressures from about 2.0 - 3.5 kbar. Consequently, its properties are... -
Structure determination of water-rich and highly metastable energy-storage ma...
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