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Negative thermal expansion in the rutile phase of ZnF2
It has recently been discovered than the rutile phase of zinc fluoride shows negative thermal expansion along all three crystallographic axes. What is highly unusual about this... -
Proton dynamics in novel organic ferroelectric materials
The vast majority of known ferroelectrics are inorganic compounds such as barium titanate and potassium dihydrogen phosphate. Contrary to naïve expectation, ferroelectricity in... -
Anomalous spin diffusion in 2D percolating magnet
This proposal is to observe single-spin diffusive motion on a two-dimensional (2D) percolating network having a fractal geometry. The random walker¿s travel times on a... -
Probing Dirac magnons in a honeycomb ferromagnet
Studying bosonic analogues of fermions in topological electron systems is one of the hottest areas. They are featured by linear band crossing points at finite energy in the... -
Order-disorder and phase transitions in the LiFeO2 cathode materials
Despite the importance of the LiFeO2 phases as cathode materials in lithium ion batteries, little is known about their crystal structures, except that they should be based on... -
Magnetic excitations from two-dimensional interpenetrating Cu framework in Ba...
The Heisenberg antiferromagnet is a well-known model used to describe the magnetic properties of layered and metal-organic Mott insulators which have been explored both... -
Multiferroic (Ferroelastic/Magnetic) Phase Transitions in KMnF3
KMnF3 perovskite undergoes 3 structural, and two magnetic phase transitions on cooling from 300 K to 2 K. Above 185 K the compound is in the aristotype structure, on cooling... -
Aza-crown-stabilized Alkali-Alkalide Systems: Solvent and metal effects on di...
We request 4 days on IRIS to investigate the diffusional and rotational dynamics of the alkalide forming, fully methylated aza-crown hexamethyl-hexacyclen (HMHC) in... -
Vibrational density of states in ammonium hexachlorometallates.
The piloting VESUVIO experiments RB820478, RB610497 on (NH4)2PdCl6 and (NH4)2TeCl6 and RB 10067 on (ND4)2PdCl6 have shown that: (i) the H/D dynamics in NH4+/ND4+ is largely... -
Atomic structure of formamidinium lead iodide perovskite
New perovskite phases containing lead and halogens with a molecular cation are providing new options for materials in solar cells, giving unusually high efficiencies in... -
Inelastic Neutron Scattering study on Co-doped CeCu2Ge2
The AFM ground state of CeCu2Ge2 can be continuously suppressed by Co doping and NFL type behavior is seen around the critical concentration xc = 0.6. The electrical resistivity... -
Neutron diffraction and µSR investigation on YbPd
YbPd crystallizes in the cubic CsCl-type structure and reported to have magnetically ordered ground state with the mixed valence of the Yb ion. Further, it under goes through... -
In-Situ Quasi-Elastic Neutron Scattering Study of a Gas Loaded Indium-Carboxy...
We request 8 days on IRIS to study the diffusion of adsorbed H2 gas and C2-hydrocarbons molecules within a gated indium-based porous metal-organic framework (MOF) as a function... -
Neutron Diffraction study of Highly Frustrated SrEr2O4
We propose to measure the neutron diffraction pattern of a single crystal sample of SrEr2O4, using the WISH diffractometer. As the magnetic Er ions in this compound are linked... -
Correlation of structures, compositions and magnetism of copper-deficient lay...
This experiment will investigate three related systems which contain copper deficient anti-fluorite-type copper sulfide layers. The overall aim is to correlate magnetic and... -
Magnetism and structural distortions in the Sr(2-x)Ba(x)NiOsO6 system
The magnetism of double perovskites can be amazingly sensitive to subtle distortions of their structures. Previous studies have shown that Ca2NiOsO6 is a ferrimagnet, Sr2NiOsO6... -
Correlation between crystalline and magnetic structures, and polarization in ...
TbMnO3 attracts special attention due to its large magnetoelectric coupling, polarization flop and ferro-paramagnetic phase transition, both induced by magnetic field. Despite... -
Magnetic excitations in Er2Zr2O7 and Er2Ir2O7
The rare-earth oxides of the general formula A2B2O7, with A being a rare-earth ion (Er in our case) and B a d- or p-metal (B = Zr or Ir), have been extensively studied for their... -
Effects of external and chemical pressure on the magnetovolume effects in Ba3...
Ba3BiIr2O9 and Ba3BiRu2O9 undergo very unusual structural transitions at 74 and 176 K respectively, with instantaneous negative thermal expansion of up to 1% in the Ir compound.... -
Vibrational density of States and Occupational Disorder in the Halogenomethanes
Halogenomethane derivatives exhibit thermally induced solid¿solid phase transitions before melting that are attributed to the ability to gain rotational degrees of freedom in...