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Heterogeneous hydrogenation in continuous flow followed by NMR and total neut...
It has been estimated that 80-90 % of chemical processes use catalysis in at least one step of the production process. Their use increases the energy efficiency of the process... -
Understanding the effect of pressure on ionic liquid structure
There are few studies on the effect of pressure on ionic liquids; however, there are indications that, at pressures around 1.0 GPa, these systems undergo a significant change in... -
Amorphous Micrometre-Sized Water Ice Particles for Planetary Science Experime...
We request 5 days on NIMROD to characterise the pressure and temperature dependent properties of amorphous icy particles generated in liquid ethane, as they will be used in... -
Investigating the uptake of cyclohexanone oxime in hierarchically-porous cata...
Sustainable technologies for polymer manufacture remain an important target of catalyst research. Thus, we have developed a hierarchically-porous (HP) SAPO (containing... -
Are ice particles in the laboratory "good" analogues for collision studies of...
With the discovery of almost 3000 exo-planets it is clear that planet formation is a by-product of star formation, yet in the micron cm size range, where relative velocities... -
Modes of pi-stacking in neat and aqueous solutions of 1-naphthyl-3-methylimid...
The proposed work continues our investigations of the structure, aggregation, self-assembly and ion pairing of ionic liquids in the neat state, at interfaces, and in solutions.... -
Insight into the adsorbed water layer of hydration shells around iron oxide n...
With this proposal we want to study the (deuterated) hydration shell of facetted iron oxide nanoparticles (IONPs). IONPwater interfaces are of great importance for biomedical... -
Local atomic and magnetic structure of multiwall carbon nanotubes continuousl...
We propose to study a novel nanostructure consisting of multi-walled carbon nanotubes continuously filled with a single crystal of Fe3C using total neutron scattering on NIMROD.... -
Neutron Scattering and Structural Measurements of CO2 and CD4 Adsorption in M...
Shale is an increasingly viable source of economic quantities of natural gas worldwide. Most of the gas is contained within the fine pores, thus characterizing accessibility and... -
Unraveling the short-range magnetism in intermetallic core-shell nanoparticle...
Magnetic nanoparticles (NPs) are nowadays investigated comprehensively. Our TbCu2 NPs show a core-shell structure in which the core orders antiferromagnetically and the shell is... -
The effect of confinement on the structure of alcohol-water mixtures
Compared with gas phase reactions, liquid phase catalytic processes are complex due to the effect of the solvent. The solvent controls many aspects of the overall reaction... -
First insights into the hydration of the nootropic drug piracetam by neutron ...
The proposal seeks to investigate the structure and hydration of the nootropic drug piracetam in aqueous solutions by neutron scattering on the SANDALS instrument, with... -
Investigating the diffusion of C6 cyclic and aromatic hydrocarbons in Pt/MCM-41
Diffusion of a range of cyclic hydrocarbons relevant to the nylon production process will be measured in the potential catalyst Pt/MCM-41 in the context of the benzene... -
Liquid Structure of Amino Acid Ionic Liquids Based on a Spectator Cation
Ionic liquids based on biocompatible ions such as amino acids are of significant interest since they offer access to a lower-cost and lower-toxicity family of green solvents for... -
New morphologies of functional metal oxide nanoparticles
The morphologies of metal oxide nanoparticles may be varied by imposition of an electric field during growth. These varying morphologies give improved efficiencies for gas... -
Amorphous Micrometre-Sized Water Ice Particles for Planetary Science Experime...
We request 2 days on SANDALS to characterise the temperature dependent properties of amorphous icy particles as they will be used in a more detailed study on NIMROD in Feburary... -
When like-charged ions attract: How OH-defects influence the size and distrib...
This study will probe the liquid nanostructures of mixtures of two ionic liquids, 4-(hydroxybutyl)pyridinium-bis(trifluorosulfonyl)-imide ([HOC4Py]NTf2) and... -
Investigating the diffusion component of the phenyacetylene hydrogenation rea...
Liquid phase heterogeneous catalysis makes up one the largest proportions of chemical industry. The catalysed phenyacetelene hydrogenation reaction is of great interest as it is... -
How is the nanoscale structure of Amorphous Solid Water (ASW) impacted by the...
This experiment will determine how the structure and porosity of Amorphous Solid Water (ASW) changes when the ice is contaminated by adsorbate molecules. ASW is a porous... -
Role of DMSO in Ionic Liquid / DMSO Mixtures
This proposal aims to study the interactions within a prototypical ionic liquid / co-solvent system. Such systems are currently under investigation as potential solvating media...
