Gridded annual anthropogenic emission of CO2(fossil,bio), CH4 and three air pollutants (NOx, CO, PM) for the City of Munich for the period 2019-2024, as prepared and developed for the H2020 project ICOS Cities PAUL Pilot Applications in Urban Landscapes, and described in Deliverable 1.2 (https://fileshare.icos-cp.eu/s/3ksc9Jiscqw4nWo) and the related GitHub Repository https://github.com/tum-esm/tum-mci. The inventory is a combined product of bottom-up estimates based on local data (currently for GNFR sectors A-Power Plant, C-Stationary Combustion, F-Road Transport, Human Respiration) developed by the Technical University of Munich (TUM) and a spatially downscaled regional inventory (TNO-GHGco V4.1) for the remaining sectors provided by TNO. The unit is "kg yr-1 cell-1" across all files. The spatial resolution is 1/600° x 1/1200° (about 100m x 100m). Please note that no PM and CH4 emissions are included in sector GNFR A. This dataset is complemented by Aigner, P., Althammer, T., Chen, J., Denier van der Gon, H., Hinderer, J., Kühbacher, D., Suhendra, M., Super, I., Yirtar, B., 2025. Temporal Activity Profiles for the City of Munich (2019-2024). https://doi.org/10.18160/Z2CB-JKQ2.