Understanding the Influence of Acidity on the Diffusion of Water in Zeolites

DOI

The conversion of methanol to hydrocarbons over ZSM-5 zeolite catalysts exists within the framework of obtaining gasoline fuel and high-value petrochemicals such as propylene sustainably from bio-feedstock. The initial steps of the reaction are highly debated as methanol and its derivative, dimethyl ether, and water compete for ZSM-5 catalytic active sites. Also, water reduces the reaction rate and increases ZSM-5 lifetime. This work aims to understand how the movement of water affects this competitive bonding process and catalyst stability. We aim to quantify and compare the mobility of water in ZSM-5 with different acidic site densities (Si/Al = 25, 36 and 135). The experimental data obtained will further be quantitatively analysed to decouple the processes of bonding and release from the active sites. This is required to understand and predict the behaviour of ZSM-5 zeolite catalysts.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920014-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/109730666
Provenance
Creator Professor Andre van Veen; Mr Oluwatoyin Omojola; Dr Ian Silverwood; Miss Sandra McHugh; Mr Alex Porter; Dr Alexander O'Malley
Publisher ISIS Neutron and Muon Source
Publication Year 2023
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Construction Engineering and Architecture; Engineering; Engineering Sciences; Natural Sciences
Temporal Coverage Begin 2020-02-27T08:30:00Z
Temporal Coverage End 2020-03-02T08:30:00Z