Stable carbon isotopic analyses of n-alkanes and the calculated C4 plant-derived fractions in the dust samples


Atmospheric dust samples collected along a transect off the West African coast have been investigated for their lipid content and compound-specific stable carbon isotope compositions. The saturated hydrocarbon fractions of the organic solvent extracts consist mainly of long-chain n-alkanes derived from epicuticular wax coatings of terrestrial plants. Backward trajectories for each sampling day and location were calculated using a global atmospheric circulation model. The main atmospheric transport took place in the low-level trade-wind layer, except in the southern region, where long-range transport in the mid-troposphere occurred. Changes in the chain length distributions of the n-alkane homologous series are probably related to aridity, rather than temperature or vegetation type. The carbon preference of the leaf-wax n-alkanes shows significant variation, attributed to a variable contribution of fossil fuel- or marine-derived lipids. The effect of this nonwax contribution on the d13C values of the two dominant n-alkanes in the aerosols, n-C29 and n-C31 alkane, is, however, insignificant. Their d13C values were translated into a percentage of C4 vs. C3 plant type contribution, using a two-component mixing equation with isotopic end-member values from the literature. The data indicate that only regions with a predominant C4 type vegetation, i.e. the Sahara, the Sahel, and Gabon, supply C4 plant-derived lipids to dust organic matter. The stable carbon isotopic compositions of leaf-wax lipids in aerosols mainly reflect the modern vegetation type along their transport pathway. Wind abrasion of wax particles from leaf surfaces, enhanced by a sandblasting effect, is most probably the dominant process of terrigenous lipid contribution to aerosols.

Altitude=15m: Sampling was conducted with Andersen high-volume particulate matter dust samplers installed on the ship's tower.

Supplement to: Schefuß, Enno; Ratmeyer, Volker; Stuut, Jan-Berend W; Jansen, J H Fred; Sinninghe Damsté, Jaap S (2003): Carbon isotope analyses of n-alkanes in dust from the lower atmosphere over the central eastern Atlantic. Geochimica et Cosmochimica Acta, 67(10), 1757-1767

Related Identifier
Metadata Access
Creator Schefuß, Enno (ORCID: 0000-0002-5960-930X); Ratmeyer, Volker; Stuut, Jan-Berend W ; Jansen, J H Fred; Sinninghe Damsté, Jaap S
Publisher PANGAEA
Publication Year 2003
Rights Creative Commons Attribution 3.0 Unported;
OpenAccess true
Language English
Resource Type Supplementary Dataset; Dataset
Format text/tab-separated-values
Size 350 data points
Discipline Geosciences; Natural Sciences
Spatial Coverage (-17.930W, -10.690S, 12.500E, 30.440N)
Temporal Coverage Begin 1998-02-15T00:00:00Z
Temporal Coverage End 1998-03-11T00:00:00Z