Bulk geochemistry of composite sediment core ROD11 from the crater basin of Rodderberg, Germany

DOI

Bulk geochemistry characterizes sediment composition and supports palaeoclimatic reconstruction of glacial/interglacial cycles for the Middle Pleistocene sediment record from the crater basin of Rodderberg, Germany. A sediment record measuring 72.8 m in length was retrieved by employing wire-line drilling techniques, utilising 3 m-long liners, from the silted-up crater basin of Rodderberg (East Eifel Volcanic Field) in the vicinity of the city of Bonn, Germany. The composite record ROD11 was subjected to continuous analysis for bulk geochemistry (total carbon, total nitrogen, total sulphur) with 10 cm spatial resolution employing a CNS analyser (EuroEA, Eurovector). Additionally, the analysis of total organic carbon was carried out with the same setup but after the destruction of carbonates with 3% and 20% sulphuric acid. The difference between total carbon and total organic carbon yields total inorganic carbon, a proxy parameter for carbonates. The calculation of organic matter was performed by multiplication of total organic carbon with a value of 2.13, in accordance with the methodology proposed by Dean (1974). The calculation of carbonaceous matter was accomplished by multiplying total inorganic carbon values with 8.33, in order to account for the stoichiometric mass change from C to CaCO3. Minerogenic matter was determined as the difference between 100 and the sum of organic matter and carbonaceous matter. These parameters enhance the palaeoclimatic interpretation for the past 430 ka. Valued by multiple dating techniques, this terrestrial record provides an environmental reconstruction since the Middle Pleistocene.

Identifier
DOI https://doi.org/10.1594/PANGAEA.975227
Related Identifier References https://doi.org/10.1016/j.quascirev.2022.107932
Related Identifier References https://doi.org/10.1016/j.quageo.2024.101535
Related Identifier References https://doi.org/10.1002/jqs.3654
Related Identifier References https://doi.org/10.1127/1860-1804/2014/0071
Related Identifier IsDocumentedBy https://doi.org/10.1306/74D729D2-2B21-11D7-8648000102C1865D
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.975227
Provenance
Creator Zolitschka, Bernd ORCID logo; Frechen, Manfred
Publisher PANGAEA
Publication Year 2025
Funding Reference German Research Foundation https://doi.org/10.13039/501100001659 Crossref Funder ID 420499726 https://gepris.dfg.de/gepris/projekt/420499726 Suborbital-scale climate variability of the last three glacial/interglacial cycles – high-resolution environmental reconstructions from sediments of the Rodderberg crater (Germany)
Rights Licensing unknown: Please contact principal investigator/authors to gain access and request licensing terms; Data access is restricted (moratorium, sensitive data, license constraints)
OpenAccess false
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 6526 data points
Discipline Earth System Research
Spatial Coverage (7.192 LON, 50.645 LAT); Rodderberg, North Rhine-Westphalia, Germany
Temporal Coverage Begin 2011-11-01T00:00:00Z
Temporal Coverage End 2012-01-31T00:00:00Z