Dynamics of Polymer Rings

DOI

This proposal is part of our research efforts aimed at the understanding of the static and dynamic properties of cyclic polymers and their comparison to linear chains. Previous QENS experiments suggest similarity between the local dynamics of cyclic and linear poly(dimethylsiloxane)s (PDMSs), at relatively high molar mass values (ca. 10000). However, considerable differences have been seen by us for very small rings/linear chains. These appear to be consistent with other experimental observations but a systematic study is needed to confirm our results. Molar mass effects on local dynamics of rings have not been reported in the literature on this or other systems.

Identifier
DOI https://doi.org/10.5286/ISIS.E.82360094
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/82360094
Provenance
Creator Dr Ian Silverwood; Dr Mark Telling; Dr Valeria Arrighi; Professor Dame Julia Higgins; Dr simona gagliardi; Miss Jenny Taylor
Publisher ISIS Neutron and Muon Source
Publication Year 2019
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2016-09-21T08:00:00Z
Temporal Coverage End 2016-09-25T08:00:00Z