Hydrogen isotopes of n-alkane biomarkers and brGDGT temperatures from Lake Tulane, Florida, USA

DOI

This dataset includes temperatures derived from branched glycerol dialkyl glycerol tetraethers (brGDGTs) and regional hydrology changes reconstructed from hydrogen isotope ratios (δ2H) of n-alkanes extracted from a lacustrine sediment core from Lake Tulane, Florida, USA. In 1994, 8 cores from 6 locations (2 complete overlaps) were acquired from a transect along the north basin of Lake Tulane. Cores were taken with a 7.5-cm diameter Wright square-rod piston corer from an anchored raft. Separately, a single surface-water interface core was acquired from the north basin of Lake Tulane in 2010. brGDGTs and n-alkanes were extracted from archived core sections at 8-10 cm intervals in August of 2018 and from the surface-water interface core at 5 cm intervals in August of 2019. The archived core interval spanned Heinrich Stadials 4-2 (41,000-17,000 BP) and the surface-water interface core spanned 78-0 BP. brGDGT distributions from both cores were measured via atmospheric pressure chemical ionization high-performance liquid chromatography-mass spectrometry (APCI/HPLC–MS), and hydrogen isotope ratios of n-alkanes were measured on a Thermo Trace GC Ultra coupled to a Thermo Electron Delta V Advantage IRMS with an Isolink combustion furnace. The brGDGT data was converted to degrees Celsius (°C) following the open-sourced code provided in O'Beirne et al. (2023, doi:10.1016/j.gca.2023.08.019). Hydrogen isotope results are given in the conventional δ-notation. A proxy for seasonal precipitation and aridity (ε(C29-C23)) was created, which reflects the difference between the δ2H values of aquatic n-alkanes (δ2HC23) and terrestrial leaf wax δ2H values (δ2HC29) using the following equations: (1) α = (1000 + 𝛿2HC29)/(1000 + 𝛿2HC23), and (2) ε(C29-C23) = (α -1) x 1000.

Identifier
DOI https://doi.org/10.1594/PANGAEA.989435
Related Identifier References https://doi.org/10.1016/j.gca.2023.08.019
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.989435
Provenance
Creator Arnold, T Elliott
Publisher PANGAEA
Publication Year 2026
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 269 data points
Discipline Earth System Research
Spatial Coverage (81.500 LON, 27.586 LAT); Florida, USA