Mechanism of charging metal oxide colloids in non-polar solvents

DOI

The aim is to characterize the surface of charged metal oxide colloids in non-polar liquids. Surfactant is added to stabilize charges on particle surfaces, and is present as inverse micelles. Acid-base interactions, arising from proton transfer from the colloid surface to inverse micelles are one mechanism proposed for the origin of particle surface charge in non-polar solvents. Recent results of the electrophoretic mobility with metal oxide nanoparticles support this mechanism, but there have been no studies of the structure these particle/surfactant surfaces.Contrast-variation SANS (CV SANS) will be used to determine how surfactant inverse micelles interact with model metal oxide colloids. By using deuterated surfactant (D-AOT) with associated H2O as well as H-AOT with associated D2O, it will be possible to determine whether proton (deuteron) transfer occurs, and if so, whether the surfactant adsorbs appreciably on the surface. By systematically varying the metal oxide type and surfactant concentration, this study will reveal any universal behavior.

Identifier
DOI https://doi.org/10.5291/ILL-DATA.9-10-1326
Metadata Access https://data.ill.fr/openaire/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=10.5291/ILL-DATA.9-10-1326
Provenance
Creator Yan, Ci; James, Craig; Smith, Gregory; Grillo, Isabelle; Eastoe, Julian; Navarro, Miguel; Brown, Paul; Alexander, Shirin
Publisher Institut Laue-Langevin
Publication Year 2014
Rights OpenAccess; info:eu-repo/semantics/openAccess
OpenAccess true
Representation
Resource Type Dataset
Size 401 MB
Version 1
Discipline Particles, Nuclei and Fields