Investigating the diffusion of industrially-significant cyclic oximes in solid-acid catalysts

DOI

The aim is to contrast the diffusion of cyclohexanone oxime, cyclododecanone oxime and their corresponding amides in both the smaller pore MFI framework and the larger pore framework of Zeolite-Y and SAPO-37 (FAU). These are relevant to the industrial production of nylon monomers. Corresponding catalytic data is already in-place, using the novel low-temperature liquid Beckmann rearrangement method, and measuring the diffusion coefficients through neutron scattering will facilitate structure-activity relationships to be established.

Identifier
DOI https://doi.org/10.5286/ISIS.E.49916481
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/49916481
Provenance
Creator Professor Richard Catlow; Professor Robert Raja; Dr Victoria Garcia Sakai; Dr Matthew Potter; Dr Alexander O'Malley; Dr Peter Wells; Dr Ian Silverwood; Miss Stephanie Newland; Mr Matthew Potter
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2014-06-04T23:00:00Z
Temporal Coverage End 2014-06-10T23:00:00Z