Synthesis and Single Crystal Structure Solution of Carbonic Acid (H2CO3) at Elevated Pressures

DOI

The aim of this project is the single crystal structure determination and characterisation of phase transitions of crystalline carbonic acid (H2CO3) at high pressures. Understanding structure-property relations of H2CO3 is of significant interest not only to astrophysics, as H2CO3 is likely to be present on the surface and in the interiors of icy moons (e.g. Ganymede) or ice giants (e.g. Uranus), but also to solid state chemistry, as it is a molecular compound which has led to a number of mutually contradictory studies, e.g. regarding an assumed polymorphism. Up to now no single crystal diffraction data of H2CO3 has been reported and its structure even at low pressures (< 10 GPa) is in dispute. In preliminary experiments, we synthesized H2CO3 crystals from a H2O + CO2 mixture and characterised the product by Raman spectroscopy. We now propose to determine the structure of H2CO3 in a wide pressure range (1-150 GPa).

Identifier
DOI https://doi.org/10.15151/ESRF-ES-2043623109
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/2043623109
Provenance
Creator Elena BYKOVA (ORCID: 0000-0001-8652-024X); Valentin KOVALEV ORCID logo; Loic JEGOU; Dominik SPAHR ORCID logo; Ninel SHARAPOVA; Pascal Lennert JURZICK ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2028
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields