Ferromagnetic ordering in -[Lanthanide(III)-Radical]n- coordination polymers

DOI

The molecular magnet [Sm(hfac)3(boaDTDA)]n is the first metal complex of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering and was the subject of experiment 1620139. The system is of special interest, not only as it increases the relatively small number of radical ferromagnets yet discovered, but as its cooperative properties appear to realise a model developed by McConnell which ascribes intermolecular ferromagnetic interactions to overlaps from regions with opposite spin density. Here we propose to compete our muSR study of this system by measuring an analogous system where the lanthanide ion is La(III) and whose magnetic ground state is currently unknown.

Identifier
DOI https://doi.org/10.5286/ISIS.E.87839455
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/87839455
Provenance
Creator Miss Belinda Eglin; Dr Thomas Hicken; Dr James Lord; Miss Mari Cole; Dr Kevin Franke; Dr Francis Pratt; Professor Stephen Blundell; Professor Kathryn Preuss; Dr Matthew Worsdale; Dr Ben Huddart; Professor Tom Lancaster
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences; Physics
Temporal Coverage Begin 2018-03-01T09:00:00Z
Temporal Coverage End 2018-03-03T09:00:00Z