Interpenetration of surface-anchored polymers: structures for stabilisation and lubrication

DOI

Polymeric surface coatings are widely used to tailor the properties of surfaces. At the microscopic level, polymer layers provide steric stabilisation that gives colloidal stability to a system, while on macroscopic surfaces, polymer brushes have been shown to significantly reduce the friction relative to bare surfaces. Numerical self-consistent field theory calculations predict that two neutral polymer brushes or two like-charged polymer brushes do not interpenetrate when pushed against each other. Conversely, a charged/uncharged system would show a significant degree of interpenetration. In these experiments we will bring an uncharged polymer brush against brushes of various charge densities using our confinement cell. We will interpret the observed structures with reference to colloidal stability in mixed-stabiliser systems and controllable lubrication.

Identifier
DOI https://doi.org/10.5286/ISIS.E.42588975
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/42588975
Provenance
Creator Dr Stuart Prescott; Professor Rob Richardson; Dr Wiebe De Vos; Dr Stephen Abbott; Professor Terence Cosgrove; Dr Laura Mears
Publisher ISIS Neutron and Muon Source
Publication Year 2016
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2013-10-09T23:00:00Z
Temporal Coverage End 2013-10-13T23:00:00Z