In-situ concentrations of iron and aluminium in CXD31 sub-samples

DOI

Iron (Fe) availability in the ocean is strongly influenced by external inputs, including atmospheric deposition, sediment dissolution, and hydrothermal fluxes. To investigate long-term changes in Fe supply, we report in-situ measurements of Fe and aluminium (Al) concentrations from sub-samples of a Fe-Mn crust (CXD31) from the North Pacific Ocean, covering the last ~23 Myr. Iron concentrations exhibit a long-term increasing trend superimposed by several pronounced peaks, while Al concentrations co-vary with Fe during specific intervals, indicating variable terrigenous input. Periods of elevated Fe and Al concentrations at ~16.9, ~11.6, and ~2.7 Ma suggest intensified delivery of lithogenic material to the open ocean. We interpret these peaks as reflecting enhanced atmospheric dust fluxes associated with major phases of Asian inland aridification. The Fe–Al concentration dataset provides an independent geochemical archive for reconstructing variations in external Fe supply and supports a strong link between continental climate evolution and trace metal accumulation in the North Pacific.

Identifier
DOI https://doi.pangaea.de/10.1594/PANGAEA.991014
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.991014
Provenance
Creator Chu, Yongzhi ORCID logo; Li, Xiaohu; Xie, Ruifang C ORCID logo; Conway, Tim M ORCID logo; Xu, Antao ORCID logo; Dong, Yanhui
Publisher PANGAEA
Publication Year 2026
Funding Reference National Key Research and Development Program of China https://doi.org/10.13039/501100012166 Crossref Funder ID 2023YFC2811205 ; National Key Research and Development Program of China https://doi.org/10.13039/501100012166 Crossref Funder ID 2023YFC2811305 ; National Natural Science Foundation of China https://doi.org/10.13039/501100001809 Crossref Funder ID NSFC 42376035 Tracing water column export production and remineralization using Ba and Cd isotopes; National Natural Science Foundation of China https://doi.org/10.13039/501100001809 Crossref Funder ID U2244222 ; Second Institute of Oceanography, State Oceanic Administration https://doi.org/10.13039/501100013288 Crossref Funder ID SZ2563
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Dataset
Format text/tab-separated-values
Size 416 data points
Discipline Biogeochemistry; Biospheric Sciences; Geosciences; Natural Sciences
Spatial Coverage (173.200 LON, 19.900 LAT)