Complex structural modelling of amorphous [Au(SPh)]n and [M(1,2,4-triazole)2(H2PO4)2]n phase change coordination polymers for next generatio

DOI

Coordination polymers (CPs) with reversible phase changes between amorphous and crystalline states have recently become of interest for potential Phase-Change Memory applications. Efficient CPs have to exist in amorphous and crystalline phases with remarkably different optical, conductive or electrical properties which can be reversed by the application of an external stimuli to get the set/reset outputs (Fig. 1). Thus their physical properties are strongly affected by the presence or absence of long range order, defects or different connectivities. While the structures of the crystalline forms have been well characterized by traditional crystallographic approaches relying on the periodicity of the lattice, the atomic connectivity of CPs in the amorphous state is not yet understood. Thus, we propose to perform a total scattering experiment of the two promising CPs, [Au(SPh)]n and [M(1,2,

Identifier
DOI https://doi.org/10.5286/ISIS.E.99688637
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/99688637
Provenance
Creator Dr Ron Smith; Dr Aude Demessence; Dr Maria Diaz-Lopez; Dr Helen Playford
Publisher ISIS Neutron and Muon Source
Publication Year 2021
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2018-12-03T08:00:00Z
Temporal Coverage End 2018-12-08T09:29:23Z