Proton vibrations in lithium imide studied through incoherent inelastic neutron scattering

DOI

We propose to measure the incoherent neutron spectra of lithium amide (LiNH_2) and imide (Li_2NH) at low temperature (T<20 K). These two substances belong to the Li-H-N system, which has been recently considered for on-board hydrogen storage applications. However, while the the room-temperature crystal structure of the former compound is well established, that of the latter is still highly controversial, with at least six options fully or partially compatible with the diffraction experimental findings (both x-ray and neutron). Given our experience with other ionic hydrides, we believe that incoherent neutron spectra could provide unique information on the proton vibrational dynamics and so they could complement the aforementioned diffraction data, helping (together with appropriate DFT simulations) to shed more light on the elusive lithium imide crystal structure.

Identifier
DOI https://doi.org/10.5286/ISIS.E.24068474
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/24068474
Provenance
Creator Dr Anibal Ramirez-Cuesta; Dr Antonino Pietropaolo; Dr Marco Zoppi; Dr Daniele Colognesi; Dr Lorenzo Ulivi
Publisher ISIS Neutron and Muon Source
Publication Year 2012
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2009-05-31T08:32:57Z
Temporal Coverage End 2009-05-31T22:04:31Z