Measurement of oxide ion mobility in fast ion conductors.

DOI

The aim of this work is to determine the oxygen mobility in fast ion conducting oxides using quasi elastic neutron scattering in combination with molecular dynamics studies. Previous work has indicated that broadening of the QENS signal occurs on heating of CeNbO4. Due to the nature of the phase evolution in this material the interpretation proved challenging. In this work we intend to prove the use of the technique in well understood materials: yttria stabilised zirconia and delta-Bi2O3. Measurements will be made as a function of temperature and the data correlated with ionic diffusion. As a result of this work we will be able to extend this technique to a wider range of materials, including those that cannot be characterised by other conventional techniques.

Identifier
DOI https://doi.org/10.5286/ISIS.E.54816390
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/54816390
Provenance
Creator Mr Cheng Li; Dr Sanghamitra Mukhopadhyay; Professor Stephen Skinner
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2014-07-30T23:00:00Z
Temporal Coverage End 2014-08-04T23:00:00Z