In Operando Investigation of the Gate Opening Process in Metal Organic Frameworks

DOI

Metal-organic frameworks (MOFs) are crystalline, modular, and porous materials used in catalysis, gas separation, and storage. Some MOFs exhibit "gate-opening" behavior, where structural changes upon gas exposure allow selective separation via preferential coordination, aiding in the recovery of gases like helium and argon. However, the mechanisms behind gate-opening, such as the initiation site and required gas penetration depth, remain unclear. This proposal aims to use Bragg coherent diffraction imaging (BCDI) to observe these structural changes in real-time. By varying nitrogen gas pressure around the gating threshold, we will visualize the crystal's transformations at each pressure step through diffraction peak reconstructions. This novel approach offers a detailed view of the gate-opening process beyond the reach of traditional techniques, providing insights to optimize MOF design for enhanced gas separation and industrial applications.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-2104240744
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/2104240744
Provenance
Creator Tao ZHOU ORCID logo; Dina SHEYFER ORCID logo; Jiangtao ZHAO; Tugba ISIK ORCID logo; Nathan FLANDERS; Stephan HRUSZKEWYCZ
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2028
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields