Desymmetrization Strategy to Achieve Triptycene-Based 3,6-Dimethoxytriphenylenes via Oxidative Cyclodehydrogenation [Data]

DOI

To achieve a highly symmetric triptycene based hexamethoxytriphenylene in high yield of 97 %, a less symmetric triptycene (C3v) is necessary as precursor for cyclodehydrogenative Scholl-type oxidation, by taking into account the regioselectivity of the C-C bond formation controlled by attached methoxy groups. In addition, Scholl-type oxidations and photochemical reactions are compared.

Identifier
DOI https://doi.org/10.11588/data/OH6757
Related Identifier https://doi.org/10.1002/ejoc.202001073
Metadata Access https://heidata.uni-heidelberg.de/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.11588/data/OH6757
Provenance
Creator Reinhard, Dennis; Rominger, Frank; Mastalerz, Michael
Publisher heiDATA
Contributor Mastalerz, Michael
Publication Year 2022
Funding Reference Deutsche Forschungsgemeinschaft SFB 1249 (TP-A04)
Rights info:eu-repo/semantics/openAccess
OpenAccess true
Contact Mastalerz, Michael (Institute of Organic Chemistry, Heidelberg University)
Representation
Resource Type Dataset
Format application/zip
Size 85599933; 96664566; 90066895; 84994255; 92131813; 90480926; 87514072
Version 1.1
Discipline Chemistry; Natural Sciences