Understanding the interactions between organic template and metal cations to assemble zeolite frameworks

DOI

Zeolites are highly crystalline aluminosilicate materials which are characterised by their microporosity and open framework structures. Due to their porosity, zeolites have a variety of applications including catalysis, hydrocracking, ion-exchange and as drug release materials. We intend to use inelastic neutron scattering (INS) spectroscopy on the TOSCA instrument to probe the OSDA species in the zeolite structures. In each case a different metal cation can be coordinated within the cavity of the 18-crown-6 ether molecule, therefore influencing the molecular vibrations. In addition to this, we aim to observe vibrations of the cation within the cavity and the cations within the framework. This will give an indication as to what cation is occupying the crown’s cavity, allowing us also to identify its possible shape and interaction with the zeolite framework.

Identifier
DOI https://doi.org/10.5286/ISIS.E.86778195
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/86778195
Provenance
Creator Ms Mero-Lee Cornelius; Miss zoe Jones; Dr Huan Doan; Dr Asel Sartbaeva; Dr Jeff Armstrong; Dr Antony Nearchou
Publisher ISIS Neutron and Muon Source
Publication Year 2020
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2017-10-01T08:00:00Z
Temporal Coverage End 2017-10-05T10:34:46Z