A study of ammonia kinetics in Zr-based metal-organic frameworks

DOI

Combined with computational modeling, in situ quasi-elastic neutron scattering (QENS) at OSIRIS beamline will be employed to study ammonia transport and self- diffusivities at 298 K in the host structure of UiO-67 metal-organic frameworks (MOFs) as a function of increased ammonia loading. Results will be used to interpret the stepped ammonia sorption isotherms of these materials, which may open a new perspective of structure-adsorption relationships in MOF materials. Findings will also enable our rational design of Zr-based MOFs for efficient catalytic ammonia decomposition to produce hydrogen for fuel cell applications.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920263-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/108677769
Provenance
Creator Dr Pu Zhao; Dr Sanghamitra Mukhopadhyay; Professor Edman Tsang; Miss TATCHAMAPAN YOSKAMTORN; Ms Kirsty Purchase; Mr Guangchao Li; Mr Simson Wu; Mr Yiyang Li; Mr Huihuang Fang; Miss Ally King; Mr Konstantin Lebedev
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Construction Engineering and Architecture; Engineering; Engineering Sciences; Natural Sciences
Temporal Coverage Begin 2019-11-28T08:02:56Z
Temporal Coverage End 2019-12-05T08:30:00Z