Composing a Molecular Symphony A catalytically active small organic molecule oscillator

DOI

This dataset contains the supplementary data belonging to the PhD thesis of Matthijs ter Harmsel titled ‘Composing a Molecular Symphony’. It consists of data related to two projects. The first project is an investigation of the mechanism of Fmoc deprotection through Density Functional Theory (DFT). The data available here are the coordinates of optimized stationary points, Gaussian output files of geometry optimizations and output files of Internal Reaction Coordinate (IRC) calculations. The second project is the development of a catalytically active small molecule oscillator based on autocatalytic Fmoc deprotection and acetylation reactions. In order to determine at what conditions sustained oscillations could be obtained kinetic rate laws were determined for all individual reactions and a model based on Ordinary Differential Equations (ODE) was built using these rate laws. The data included here are the scripts used to explore the conditions where oscillations take place, consisting of the model and a parallelized loop running simulations varying the concentrations of all components and the flow rate, as well as the outputs of these scripts.

Identifier
DOI https://doi.org/10.34894/MRVLMN
Related Identifier https://research.rug.nl/en/publications/composing-a-molecular-symphony-a-catalytically-active-small-organ
Metadata Access https://dataverse.nl/oai?verb=GetRecord&metadataPrefix=oai_datacite&identifier=doi:10.34894/MRVLMN
Provenance
Creator ter Harmsel, M. ORCID logo; Harutyunyan, S. R. ORCID logo
Publisher DataverseNL
Contributor Groningen Digital Competence Centre
Publication Year 2023
Rights CC0 1.0; info:eu-repo/semantics/openAccess; http://creativecommons.org/publicdomain/zero/1.0
OpenAccess true
Contact Groningen Digital Competence Centre (University of Groningen)
Representation
Resource Type Dataset
Format application/pdf; application/zip
Size 293984; 1946913; 250024147; 48888293; 2499645; 5221569
Version 1.0
Discipline Chemistry; Natural Sciences