Exploding and weeping ceramics

DOI

The systematic tuning of the lattice parameters to achieve improved kinematic compatibility between phases is a broadly effective strategy for improving the reversibility, and lowering the hysteresis, of solid-solid phase transformations. Here, "kinematic compatibility" refers to the fitting together of the phases. We present an apparently paradoxical example in which tuning to near perfect compatibility in (Zr/Hf)O2-(YNb)O4 results in a high degree of irreversibility, as manifested in explosive or "weeping" behavior on cooling through the tetragonal-to-monoclinic phase transformation. In the case of weeping the polycrystal slowly and steadily falls apart at the grain boundaries. These effects occur without chemical change. Finally, tuning to satisfy a condition we term the equidistance condition results in reversible behavior with the lowest hysteresis in this system. We give evidence that all these observations are explained by a more careful analysis of compatibility of the polycrystal, accounting for sample shape. These results show that an extreme diversity of behaviors, from reversible to explosive, is possible in a chemically homogeneous system by manipulating conditions of compatibility in unexpected ways. They provide critical concepts underlying the current search for a shape memory oxide ceramic.

Identifier
DOI https://doi.org/10.24435/materialscloud:6c-hk
Related Identifier https://doi.org/10.1038/s41586-021-03975-5
Related Identifier https://archive.materialscloud.org/communities/mcarchive
Related Identifier https://doi.org/10.24435/materialscloud:kh-b3
Metadata Access https://archive.materialscloud.org/oai2d?verb=GetRecord&metadataPrefix=oai_dc&identifier=oai:materialscloud.org:911
Provenance
Creator Gu, Hanlin; Rohmer, Jascha; Jetter, Justin; Lotnyk, Andriy; Kienle, Lorenz; Quandt, Eckhard; James, Richard D.
Publisher Materials Cloud
Contributor Gu, Hanlin; Rohmer, Jascha; Jetter, Justin; Lotnyk, Andriy; Kienle, Lorenz; Quandt, Eckhard; James, Richard D.
Publication Year 2021
Rights info:eu-repo/semantics/openAccess; Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/legalcode
OpenAccess true
Contact archive(at)materialscloud.org
Representation
Language English
Resource Type info:eu-repo/semantics/other
Format text/plain; application/zip; text/markdown
Discipline Materials Science and Engineering