Hydrophobically modified nanocelluloses/starch hydrogels: Enhancing hydrophobic interactions and inclusion complex formation

DOI

This proposal aims to investigate the interaction of hydrophobically modified oxidised cellulose nanofibrils (HM-OCNF) with surfactants or soluble starch, in order to find new more environmentally friendly rheology modifiers for possible applications in personal care or agrochemicals. Hydrophobic modification via attachment of C8 or C12 hydrocarbon chains to the cellulose particle surface has been shown to result in greatly enhanced interactions with soluble starch, dramatically increasing the viscosity of these suspensions. Here we wish to determine whether the hydrophobic chains are forming inclusion complexes with the amylose-rich soluble starch, or with micelles to better understand the mechanism of interaction between these species. We will take advantage of selective deuteration of the Cn chain and the solvent to provide scattering contrast in these systems.

Identifier
DOI https://doi.org/10.5286/ISIS.E.RB1920228-1
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/108678034
Provenance
Creator Dr Marcelo da Silva; Professor Karen Edler; Mr Vincenzo Calabrese; Dr Saffron Bryant; Dr Zakir Hossain; Dr Najet Mahmoudi
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2019-12-16T08:30:00Z
Temporal Coverage End 2019-12-19T12:23:46Z