Resolving the crystal field scheme for Dy3+ in DyNiAl4

DOI

The intermetallic series RNiAl4 (R = rare earth) exhibit interesting low temperature magnetic behaviour including a variety of (in)commensurate magnetic phases and metamagnetic transitions. The large inverse magnetocaloric effect observed for TbNiAl4 offers potential for low temperature magnetic cooling and it is expected that the strong magnetic anisotropies are driven by the crystal field (CF) interaction. Recent efforts to characterise the CF using inelastic neutron scattering (INS) have been directed at ErNiAl4 as with J=15/2 the orthorhombic environment results in 8 doublets, enough to determine the 9 symmetry-allowed crystal field parameters, although to date this has not produced a unique set of parameters. To complement studies of Er, we propose to perform a detailed study of DyNiAl4 which is also J=15/2 with the aim of solving the crystal field.

Identifier
DOI https://doi.org/10.5286/ISIS.E.63527899
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/63527899
Provenance
Creator Dr Alexy Karenowska; Dr Wayne Hutchison; Dr Andrew Princep; Professor Glen Stewart; Dr Tatiana Guidi
Publisher ISIS Neutron and Muon Source
Publication Year 2018
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Natural Sciences; Physics
Temporal Coverage Begin 2015-09-21T07:00:00Z
Temporal Coverage End 2015-09-24T07:00:00Z