XRF element analysis of two sediment cores in the Andaman Sea

DOI

X-ray fluorescence (XRF) core scanning of marine and lake sediments has been extensively used to study changes in past environmental and climatic processes over a range of timescales. The interpretation of XRF-derived element ratios in paleoclimatic and paleoceanographic studies primarily considers differences in the relative abundances of particular elements. Here we present new XRF core scanning data from two long sediment cores in the Andaman Sea in the northern Indian Ocean and show that sea level related processes influence terrigenous inputs based proxies such as Ti/Ca, Fe/Ca, and elemental concentrations of the transition metals (e.g. Mn). Zr/Rb ratios are mainly a function of changes in median grain size of lithogenic particles and often covary with changes in Ca concentrations that reflect changes in biogenic calcium carbonate production. This suggests that a common process (i.e. sea level) influences both records. The interpretation of lighter element data (e.g. Si and Al) based on low XRF counts is complicated as variations in mean grain size and water content result in systematic artifacts and signal intensities not related to the Al or Si content of the sediments. This highlights the need for calibration of XRF core scanning data based on discrete sample analyses and careful examination of sediment properties such as porosity/water content for reliably disentangling environmental signals from other physical properties. In the case of the Andaman Sea, reliable extraction of a monsoon signal will require accounting for the sea level influence on the XRF data.

Supplement to: Gebregiorgis, Daniel; Giosan, Liviu; Hathorne, Ed C; Anand, Pallavi; Nilsson-Kerr, Katrina; Plaß, Anna; Lückge, Andreas; Clemens, Steven C; Frank, Martin (2020): What Can We Learn From X‐Ray Fluorescence Core Scanning Data? A Paleomonsoon Case Study. Geochemistry, Geophysics, Geosystems, 21(2)

Identifier
DOI https://doi.org/10.1594/PANGAEA.910533
Related Identifier IsSupplementTo https://doi.org/10.1029/2019GC008414
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.910533
Provenance
Creator Gebregiorgis, Daniel ORCID logo; Giosan, Liviu ORCID logo; Hathorne, Ed C ORCID logo; Anand, Pallavi ORCID logo; Nilsson-Kerr, Katrina ORCID logo; Plaß, Anna; Lückge, Andreas ORCID logo; Clemens, Steven C ORCID logo; Frank, Martin ORCID logo
Publisher PANGAEA
Publication Year 2020
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Supplementary Publication Series of Datasets; Collection
Format application/zip
Size 2 datasets
Discipline Earth System Research
Spatial Coverage (93.000W, 10.634S, 93.112E, 10.753N)