INS Studies of Olefin Reactivity in HZSM-5 Zeolite Catalysts

DOI

This proposal looks at the reactivity of propene in a commercial ZSM-5 zeolite catalyst. It builds on a previous INS study (on TOSCA) which showed that propene in this catalyst at room temperature forms long chain oligomeric carbenium cations. We will examine what happens to these oligomers when heated to higher temperatures, and what happens when propene is directly admitted to the catalyst at higher temperatures. The measurements will provide understanding of the role of olefin oligomers in the catalytic conversion of methanol to hydrocarbons, and in the conversion of olefins to middle distillate, which are both commercial processes utilising this catalyst.

Identifier
DOI https://doi.org/10.5286/ISIS.E.101133845
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/101133845
Provenance
Creator Dr Ying Li; Ms Shouying Huang; Dr Iain Hitchcock; Professor David Lennon; Professor Russell Howe; Professor Stewart Parker; Dr Alexander Hawkins; Ms Andrea Zachariou
Publisher ISIS Neutron and Muon Source
Publication Year 2022
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2019-03-20T09:00:00Z
Temporal Coverage End 2019-03-24T09:33:54Z