Anion Order in BaTaO2N

DOI

Transition metal oxynitrides with the perovskite structure type are an emerging class of functional materials with a variety of interesting optical, photocatalytic, dielectric and magnetoresistive properties that may depend upon anion order. However, the oxide/nitride ordering principles in such materials were unclear until a recent study of the representative compounds SrMO2N (M = Nb, Ta) by neutron and electron diffraction revealed a robust partial anion order. The same order has since been confirmed in NdVO2N, and in LaTaON2 with O/N interchanged. A high resolution study is requested here to discover whether BaTaO2N has this local order of cis-anion chains in two or in three dimensions.

Identifier
DOI https://doi.org/10.5286/ISIS.E.47832861
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/47832861
Provenance
Creator Professor David Keen; Miss Alex Sinclair; Professor Amparo Fuertes; Professor Paul Attfield; Mr Ashley Black; Miss Hannah Johnston
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Photon- and Neutron Geosciences
Temporal Coverage Begin 2014-03-05T00:00:00Z
Temporal Coverage End 2014-03-07T00:00:00Z