This dataset presents a mid-Infrared Diffuse Reflectance Infrared Fourier Transform Spectroscopy (mid-DRIFTS) Soil Spectral Library (SSL) for agricultural soils in Saxony, Germany. The SSL was developed using archive soil samples from the Soil Monitoring Program of the State Office for Environment, Agriculture, and Geology (LfULG). A total of 123 physicochemical soil properties (with varying availability) are included in the presented dataset, covering soil organic carbon, total nitrogen, various total and extractable elemental contents, soil pH, cation exchange capacity, particle size distribution, bulk density and soil water retention. In addition to archive samples, the dataset includes supplementary soil samples collected during an intensive sampling campaign in September 2023, which also incorporates soil physical properties data. Mid-IR spectra were recorded from 7500 cm-1 to 400 cm⁻¹, using a Bruker Alpha II DRIFT. All samples were (re-) analysed using stepped thermal analysis according to DIN 19539 / DIN EN17505. The presented SSL was built as part of the LfULG project FuE 42-Z771/2 and constitutes the foundation for integrating quantitative mid-DRIFTS as an analytical tool in Saxony's agricultural soil monitoring program.