Distribution and speciation of sulfur in foraminiferal calcite

DOI

The sulfur to calcium ratio (S/Ca) of foraminiferal calcite is currently being investigated as an indicator (proxy) of past seawater carbonate ion concentration ([CO32-]), one of the most coveted palaeo-oceanographic parameters needed to reconstruct past atmospheric CO2. Uncertainty surrounding the pathway of uptake, transport and precipitation of sulfur from seawater to foraminiferal calcite impedes the application of this proxy. We propose to investigate the micro-distribution and speciation of sulfur, and its link to Mg, to further the development of this proxy relation. Using μXRF and µXANES analysis on both hyaline and porcelaneous species of foraminifera cultured at different seawater [CO32-] conditions will 1) confirm, for the first time, if sulfur is indeed present as SO42- in foraminiferal shells and reveal how uptake of sulfur changes for different seawater [CO32-], and 2) increase our understanding of anion uptake in both hyaline and porcelaneous calcification pathways.

Identifier
DOI https://doi.org/10.15151/ESRF-ES-2216731079
Metadata Access https://icatplus.esrf.fr/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatplus.esrf.fr:inv/2216731079
Provenance
Creator Mariandrea NAJERA ROUSSELIN; Inge VAN DIJK ORCID logo; Christine BARRAS; Marine COTTE (ORCID: 0000-0002-4949-588X); Aurélia MOURET ORCID logo
Publisher ESRF (European Synchrotron Radiation Facility)
Publication Year 2028
Rights CC-BY-4.0; https://creativecommons.org/licenses/by/4.0
OpenAccess true
Representation
Resource Type Data from large facility measurement; Collection
Discipline Particles, Nuclei and Fields