Solid phase sediment and pore water data (Al, Fe, K, nitrate, organic carbon) from the Amazon continental shelf (cruise M147)

DOI

Sediment and pore water samples were collected during the M147 cruise of Research Vessel Meteor in April and May 2018. Additional sediment samples (GeoB 4417-5 and GeoB 4409-2) were collected during the M38-2 cruise in March 1997. Total element concentrations (Fe, Al, K) of the solid phase were measured after acid digestion (HF, HNO3 and HClO4) by inductively coupled plasma optical emission spectrometry (Varian ICP 720-ES). Solid phase iron speciation data were measured following single step sodium dithionite extraction (FeD) or sequential Fe extraction (FeAc, FeDith, FeOxal) by inductively coupled plasma optical emission spectrometry (Varian ICP 720-ES). Solid phase pyrite concentrations (FePy) were calculated stoichiometrically from photometrically measured S2- released via chromium(II) chloride reduction. Total organic carbon (TOC) of the sediment samples was measured in an Elemental Analyzer (Euro EA). Prior to analysis carbon bound to carbonate minerals was removed by leaching the sediment with 0.25 N HCl. Pore water nitrate concentrations were measured on board with a SEAL QuAAtro continuous flow auto analyzer. Pore water samples for dissolved element analysis were acidified with HCl to pH < 2 after sampling. Depending on the concentration range, pore water K and Fe was measured by inductively coupled plasma optical emission spectrometry (Varian 720 ES) or inductively coupled plasma mass spectrometry (Agilent 7500).

Identifier
DOI https://doi.org/10.1594/PANGAEA.950248
Related Identifier IsSupplementTo https://doi.org/10.1029/2022GC010543
Related Identifier References https://doi.org/10.1016/j.chemgeo.2020.120017
Metadata Access https://ws.pangaea.de/oai/provider?verb=GetRecord&metadataPrefix=datacite4&identifier=oai:pangaea.de:doi:10.1594/PANGAEA.950248
Provenance
Creator Vosteen, Paul; Spiegel, Timo ORCID logo; Gledhill, Martha ORCID logo; Frank, Martin ORCID logo; Zabel, Matthias ORCID logo; Scholz, Florian ORCID logo
Publisher PANGAEA
Publication Year 2022
Funding Reference Deutsche Forschungsgemeinschaft, Bonn https://doi.org/10.13039/501100001659 Crossref Funder ID 283168947 https://gepris.dfg.de/gepris/projekt/283168947 Iron Cycling in Continental Margin Sediments and the Nutrient and Oxygen Balance of the Ocean (ICONOX)
Rights Creative Commons Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Representation
Resource Type Publication Series of Datasets; Collection
Format application/zip
Size 17 datasets
Discipline Earth System Research
Spatial Coverage (-51.382W, 0.952S, -45.242E, 5.138N)
Temporal Coverage Begin 1997-03-20T12:29:00Z
Temporal Coverage End 2018-05-17T14:22:00Z