Single crystal neutron diffraction of a sigma-alkane complex: Probing C–H...Rh interactions

DOI

This experiment will provide the first single crystal neutron diffraction structure of an alkane bound to a metal centre and give insight into the mechanism of the formation of this complex in the solid-state. This would be a study of an alkane complex by single crystal neutron diffraction which has never been reported and follow the mechanism of addition of H2 (or D2) using single crystal diffraction experiments. We have the crystalline material in hand, a reliable synthetic technique and a sample that is well set-up for extended collection times. Neutron data will provided unparalleled insight into the mode of C?H activation of an alkane at a metal centre and will have additional impact in the fields of catalysis and organic synthesis. Given the nature of the research and the imminent long shut-down of ISIS, we are making this application beam-time by the Rapid Access route.

Identifier
DOI https://doi.org/10.5286/ISIS.E.49912903
Metadata Access https://icatisis.esc.rl.ac.uk/oaipmh/request?verb=GetRecord&metadataPrefix=oai_datacite&identifier=oai:icatisis.esc.rl.ac.uk:inv/49912903
Provenance
Creator Dr Amber Thompson; Dr Matthias Gutmann; Professor Andrew Weller; Dr Frederick Mark Chadwick
Publisher ISIS Neutron and Muon Source
Publication Year 2017
Rights CC-BY Attribution 4.0 International; https://creativecommons.org/licenses/by/4.0/
OpenAccess true
Contact isisdata(at)stfc.ac.uk
Representation
Resource Type Dataset
Discipline Chemistry; Natural Sciences
Temporal Coverage Begin 2014-06-19T23:00:00Z
Temporal Coverage End 2014-06-27T23:00:00Z